| 97410-00-9

• 分子结构分类: 有机化合物
• CAS: 97410-00-9
• 化学式: C₃₄H₃₆CoN₄O₄
• 分子量: 623.677
• InChiKey: BHNRBPCAWZHVDY-RGTFJSJUSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  {Cd(II)(rhodoporphyrin)} 、 cobalt(II) chloride 以 二甲基亚砜 为溶剂， 生成
  参考文献：
  名称：

  Kinetics of the metal-ligand exchange of cadmium rhodo- and pyrroporphyrins with cobalt and zinc chlorides in organic solvents

  摘要：

  Experimental data on electron absorption spectra (EASs) and the kinetics of substitution of Co2+ for the central Cd2+ ion in rhodoporphyrin complexes (CdRodP) in the reaction with CoCl2 in acetonitrile (AN) and ZnCl2 in dimethyl sulfoxide (DMSO) and the substitution of Zn2+ for Cd2+ in pyrroporphyrin complexes (CdPyrP) in the reaction with ZnCl2 in DMSO are reported and discussed. The evolution of EASs in the reaction of metal-ligand exchange and the effective and true rate constants of the exchange reaction are reported. The activation energies and activation entropies are estimated.

  DOI：

  10.1134/s0036023613060065