1-iodo-4,6,6,7,9,9,10,10,11,11,11-undecafluoro-4,7-bis(trifluoromethyl)-5,8-dioxaundecyl acetate | 1345976-75-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 1-iodo-4,6,6,7,9,9,10,10,11,11,11-undecafluoro-4,7-bis(trifluoromethyl)-5,8-dioxaundecyl acetate
• 英文别名: 4,6,6,7,9,9,10,10,11,11,11-undecafluoro-2-iodo-4,7-bis(trifluoromethyl)-5,8-dioxaundecyl acetate；[4,5,5,5-tetrafluoro-4-[1,1,2,3,3,3-hexafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propoxy]-2-iodopentyl] acetate
• CAS: 1345976-75-1
• 化学式: C₁₃H₈F₁₇IO₄
• 分子量: 678.081
• InChiKey: ZCPBWVDYFJUXQC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  35
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  21

反应信息

• 作为反应物：
  描述：

  1-iodo-4,6,6,7,9,9,10,10,11,11,11-undecafluoro-4,7-bis(trifluoromethyl)-5,8-dioxaundecyl acetate 在 potassium hydroxide 作用下， 以 正己烷 为溶剂， 反应 3.0h， 生成
  参考文献：
  名称：

  A study of the physico-chemical features of the [(perfluoroalkyl)methyl]oxirane amino derivatives based on the hexafluoropropylene oxide trimer

  摘要：

  The 1,2-epoxy-4,6,6,7,9,9,10,10,11,11,11-undecafluoro-4,7-bis(trifluoromethyl)-5,8-dioxaundecane was synthesized for the first time on the basis of the hexafluoropropylene oxide trimer. We showed that it reacted with diethylamine, morpholine, or N-methylpiperazine to afford the product of regioselective cleavage of the oxirane ring. The processing of nano-sized copper powder with a solution of the obtained hydroxyamine solution in acetone allowed the formation of the hydrophobic metal coating.

  DOI：

  10.1134/s1070363211090155
• 作为产物：
  描述：

  2,5-双(三氟甲基)-3,6-二氧杂十一氟代壬酰氟 在 sodium dithionite 、 碘 、 碳酸氢钠 、 potassium carbonate 作用下， 以 水 、 N,N-二甲基甲酰胺 、 乙腈 为溶剂， 反应 2.0h， 生成 1-iodo-4,6,6,7,9,9,10,10,11,11,11-undecafluoro-4,7-bis(trifluoromethyl)-5,8-dioxaundecyl acetate
  参考文献：
  名称：

  A study of the physico-chemical features of the [(perfluoroalkyl)methyl]oxirane amino derivatives based on the hexafluoropropylene oxide trimer

  摘要：

  The 1,2-epoxy-4,6,6,7,9,9,10,10,11,11,11-undecafluoro-4,7-bis(trifluoromethyl)-5,8-dioxaundecane was synthesized for the first time on the basis of the hexafluoropropylene oxide trimer. We showed that it reacted with diethylamine, morpholine, or N-methylpiperazine to afford the product of regioselective cleavage of the oxirane ring. The processing of nano-sized copper powder with a solution of the obtained hydroxyamine solution in acetone allowed the formation of the hydrophobic metal coating.

  DOI：

  10.1134/s1070363211090155

文献信息

• Perfluoroalkylation of unsaturated compounds in the presence of copper(II) salen complexes
  作者：Yu. S. Kudyakova、D. N. Bazhin、Ya. V. Burgart、V. I. Saloutin、O. N. Chupakhin

  DOI：10.1134/s1070428013030263

  日期：2013.3