[Zn(1,10-phenanthroline)(4-dimethylaminobenzoate)2] | 894072-95-8

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: [Zn(1,10-phenanthroline)(4-dimethylaminobenzoate)2]
• CAS: 894072-95-8；943549-06-2
• 化学式: C₃₀H₂₈N₄O₄Zn
• 分子量: 573.967
• InChiKey: ITPXOIUDKXUCNY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  zinc(II) acetate dihydrate 、 4-二甲氨基苯甲酸 、 邻菲罗啉 以 甲醇 为溶剂， 以80%的产率得到[Zn(1,10-phenanthroline)(4-dimethylaminobenzoate)2]
  参考文献：
  名称：

  Design and synthesis of 1,10-phenanthroline based Zn(II) complexes bearing 1D push–pull NLO-phores for tunable quadratic nonlinear optical properties

  摘要：

  Three Zn(II) complexes bearing 1,10-phenanthroline and one-dimensional (ID) push-pull NLO-phores with various acceptor strength as well as pi-conjugation length have been synthesized in high yields for two-dimensional (2D) nonlinear optical response. The quadratic optical nonlinearity of the ligands and the complexes are measured by the HRS technique. The ligands show small second-order optical nonlinearity (beta) comparable to the standard, para-nitroaniline (pNA). However, upon complexation with Zn(II), each complex exhibits large beta values showing the importance of metal ion in enhancing the optical nonlinear effect. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.01.043