trans-Mo2(O2CCH3)2(N,N'-di(2-methoxyphenyl)formamidine)2 | 464191-09-1

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: trans-Mo2(O2CCH3)2(N,N'-di(2-methoxyphenyl)formamidine)2
• 英文别名: trans-[Mo2(acetate)2(N,N'-di(2-methoxyphenyl)formamidinate)2]
• CAS: 464191-09-1
• 化学式: C₃₄H₃₆Mo₂N₄O₈
• 分子量: 820.562
• InChiKey: AOURWTIWGOUNMN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-Mo2(O2CCH3)2(N,N'-di(2-methoxyphenyl)formamidine)2 、 N,N'-di(6-methyl-2-pyridyl)formamidine 以 二氯甲烷 为溶剂， 以22.2%的产率得到trans-[Mo2(acetate)(N,N'-di(6-methyl-2-pyridyl)formamidinate)(N,N'-di(2-methoxyphenyl)formamidinate)2]
  参考文献：
  名称：

  Dimolybdenum complexes with mixed formamidinate ligands

  摘要：

  A series of dimolybdenum complexes containing mixed formamidinate ligand are discussed. The reactions of trans-Mo-2(O2CCH3)(2)(o-DMophF)(2) [o-HDMophF=N,N'-di(2-methoxyphenyl)formamidine] with N,N'-di(2-pyridyl)formamidine (HD pyF), N,N'-di(2-pyrimidyl)formamidine (HDpmF) and N,N'-di(6-methyl-2-pyridyl)formamidine (HDMepyF), in refluxing CH2Cl2 afforded the complexes, traps-Mo-2(O2CCH3)(DpyF)(o-DMophF)(2) (1), trans-Mo-2(O2CCH3)(DpmF)(o-DMophF)(2) (2), and trans-Mo-2(O2CCH3)(DMepyF)(o-DMophF)(2) (3), respectively. The o-DMophF(-) and DMepyF(-) ligands in these complexes adopt the s-cis, s-trans conformation, resulting in Mo-O short distances [2.889 (3) and 2.861(2) Angstrom for 1; 2.880(3) and 3.024(4) Angstrom for 2], while the DpyF(-) ligand adopts the s-cis, s-trans conformation, resulting in a Mo-N [3.208(4) Angstrom] and a Mo-H [2.90 (3) Angstrom] short distances. The reactions of trans-Mo-2(O2CCH3)(2)(o-DMophF)(2) with HDMepyF in CH3CN gave complexes 3, trans-Mo-2(O2CCH3)(DMepyF)(2)(o-DMophF) (4), and trans-Mo-2(DMepyF)(2)(o-DMophF)(2) (5). The o-DMophF(-) ligands in 4 and 5 adopt the s-cis, s-cis conformation while DMepyF(-) assumes an s-cis, s-trans conformation. Complexes 1-5 are the first dimolybdenum complexes containing mixed formamidinate ligands. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.09.019
• 作为产物：
  描述：

  乙酸钼(II)二聚体 、 lithium N,N'-di(2-methoxyphenyl)formamidinate 以 not given 为溶剂， 生成 trans-Mo2(O2CCH3)2(N,N'-di(2-methoxyphenyl)formamidine)2
  参考文献：
  名称：

  Dimolybdenum complexes with mixed formamidinate ligands

  摘要：

  A series of dimolybdenum complexes containing mixed formamidinate ligand are discussed. The reactions of trans-Mo-2(O2CCH3)(2)(o-DMophF)(2) [o-HDMophF=N,N'-di(2-methoxyphenyl)formamidine] with N,N'-di(2-pyridyl)formamidine (HD pyF), N,N'-di(2-pyrimidyl)formamidine (HDpmF) and N,N'-di(6-methyl-2-pyridyl)formamidine (HDMepyF), in refluxing CH2Cl2 afforded the complexes, traps-Mo-2(O2CCH3)(DpyF)(o-DMophF)(2) (1), trans-Mo-2(O2CCH3)(DpmF)(o-DMophF)(2) (2), and trans-Mo-2(O2CCH3)(DMepyF)(o-DMophF)(2) (3), respectively. The o-DMophF(-) and DMepyF(-) ligands in these complexes adopt the s-cis, s-trans conformation, resulting in Mo-O short distances [2.889 (3) and 2.861(2) Angstrom for 1; 2.880(3) and 3.024(4) Angstrom for 2], while the DpyF(-) ligand adopts the s-cis, s-trans conformation, resulting in a Mo-N [3.208(4) Angstrom] and a Mo-H [2.90 (3) Angstrom] short distances. The reactions of trans-Mo-2(O2CCH3)(2)(o-DMophF)(2) with HDMepyF in CH3CN gave complexes 3, trans-Mo-2(O2CCH3)(DMepyF)(2)(o-DMophF) (4), and trans-Mo-2(DMepyF)(2)(o-DMophF)(2) (5). The o-DMophF(-) ligands in 4 and 5 adopt the s-cis, s-cis conformation while DMepyF(-) assumes an s-cis, s-trans conformation. Complexes 1-5 are the first dimolybdenum complexes containing mixed formamidinate ligands. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.09.019

文献信息

• Dimolybdenum complexes containing bridging acetate ligands and anions of N,N′-di(2-methoxyphenyl)formamidine
  作者：Ying-Yann Wu、Jhy-Der Chen、Lin-Shu Liou、Ju-Chun Wang

  DOI：10.1016/s0020-1693(02)00850-2

  日期：2002.7

  Abstract The syntheses, structures and NMR spectra of quadruply bonded complexes containing three, two or one bridging acetate ligands and anions of N , N ′-di(2-methoxyphenyl)formamidine ( o -HDMophF), of the types Mo 2 (O 2 CCH 3 ) 3 ( o -DMophF) ( 1 ), trans -Mo 2 (O 2 CR) 2 ( o -DMophF) 2 (R=CH 3 , 2 ; CF 3 , 3 ; Pr n , 4 ) and Mo 2 (O 2 CCH 3 )( o -DMophF)Cl 2 (PMe 3 ) 2 ( 5 ), are discussed. Complex

  摘要包含三个，两个或一个桥联乙酸酯配体和N，N'-二（2-甲氧基苯基）甲（（o -HDMophF）阴离子的三重四元键配合物的合成，结构和NMR光谱CCH 3）3（o -DMophF）（1），反式Mo 2（O 2 CR）2（o -DMophF）2（R = CH 3，2; CF 3，3; Pr n，4）和Mo 2讨论了（O 2 CCH 3）（o -DMophF）Cl 2（PMe 3）2（5）。通过使Mo 2（O 2 CCH 3）4与过量的邻-HDMophF在THF中反应来制备配合物1。Mo 2（O 2 CCH 3）4和Mo 2（O 2 CPr n）4与过量的锂化甲form的反应分别得到配合物2和4。通过使Mo 2（O 2 CCF 3）4与邻-HDMophF在THF中反应制备配合物3，通过使1与（CH 3）3 SiCl和PMe 3在THF / CH 2 Cl 2中反应制备配合物5。记录了它们的U