3-Fluoroperylene | 77647-88-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 3-Fluoroperylene
• CAS: 77647-88-2
• 化学式: C₂₀H₁₁F
• 分子量: 270.306
• InChiKey: KHQVINBSTARIFR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  21
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-Aminoperylene 生成 苝 、 3-Fluoroperylene
  参考文献：
  名称：

  Cation radicals. 47. Reaction of perylene cation radical with fluoride ion and of perylene with xenon difluoride. Formation of 1-fluoro-, 3-fluoro-, and a difluoroperylene. Complications with chloride ion impurity

  摘要：

  DOI：

  10.1021/jo00328a035

文献信息

• Organic semiconductor formulations
  申请人：Flexterra, Inc.

  公开号：US10043978B2

  公开（公告）日：2018-08-07

  The present teachings relate to organic semiconductor formulations including an organic semiconducting compound in a liquid medium, where the liquid medium includes (1) a compound in liquid state that has electronic properties complementary to the electronic structure of the organic semiconducting compound and optionally (2) a solvent or solvent mixture for solubilizing the organic semiconducting compound. The present formulations can be used as inks in the fabrication of organic semiconductor devices.

  本发明涉及有机半导体制剂，包括液体介质中的有机半导体化合物，其中液体介质包括（1）液态化合物，该化合物具有与有机半导体化合物电子结构互补的电子特性，以及（2）用于溶解有机半导体化合物的溶剂或溶剂混合物。本制剂可用作制造有机半导体器件的油墨。
• Fluorination of polycyclic aromatic hydrocarbons: charge vs. frontier orbital control in substitution reactions of radical cations
  作者：Patrick F. King、Robert F. O'Malley

  DOI：10.1021/jo00189a031

  日期：1984.7
• Facile one-pot fluorination of polycyclic aromatic hydrocarbons (PAHs) with N-fluoro-2,4-dinitroimidazole; scope and limitation
  作者：Kenneth K. Laali、Mutsuo Tanaka、Farhad Forohar、Michael Cheng、John C. Fetzer

  DOI：10.1016/s0022-1139(98)00224-3

  日期：1998.9

  The synthetic utility of N-fluoro-2,4-dinitro-imidazole 'NF-2,4-DNI', a recently introduced NF fluorinating agent, has been tested for direct one-pot fluorination of several classes of polycyclic aromatic hydrocarbons, PAHs, namely pyrene, crowded alkyl(cycloalkyl)-pyrenes; hexahydro- and tetrahydro-pyrene; benzo[a] anthracene; benzo[a]- and benzo[e]pyrene; perylene; 2,7-di-tert-butylphenanthrene; chrysene; 9-methylanthracene and anthracene, as well as trans-15, 16-dimethyl-dihydropyrene; azuleno[1,2-a] acenaphthylene and azulene. Although the isolated yields are modest, the ease of handling of the reagent, simple operation (reflux in dichloroethane for 3 days) and the use of 1.1 equivalent of the reagent makes the procedure quite attractive for polynuclear aromatics, avoiding multi-step operations (NO2-PAH-->NH2-PAH-->N-2(+)-PAH-->F-PAH) or the use of toxic or costly reagents (CF3OF, XeF2, etc.); it provides direct one-pot access to a variety of F-PAHs that are not readily made using other fluorinating agents. (C) 1998 Elsevier Science S.A. All rights reserved.
• STEPHENSON M. T.; SHINE H. J., J.ORG. CHEM., 1981, 46, NO 15, 3139-3142
  作者：STEPHENSON M. T.、 SHINE H. J.

  DOI：——

  日期：——
• Cation radicals. 47. Reaction of perylene cation radical with fluoride ion and of perylene with xenon difluoride. Formation of 1-fluoro-, 3-fluoro-, and a difluoroperylene. Complications with chloride ion impurity
  作者：M. T. Stephenson、H. J. Shine

  DOI：10.1021/jo00328a035

  日期：1981.7