Ionic Liquid Promoted Diazenylation of <i>N</i>-Heterocyclic Compounds with Aryltriazenes under Mild Conditions
作者:Dawei Cao、Yonghong Zhang、Chenjiang Liu、Bin Wang、Yadong Sun、Ablimit Abdukadera、Haiyan Hu、Qiang Liu
DOI:10.1021/acs.orglett.6b00605
日期:2016.5.6
aryltriazenes using Brønsted ionicliquid as a promoter has been developed for the first time. Many N-heterocyclic azo compounds were synthesized in good to excellent yields at roomtemperature under an open atmosphere. Notably, the promoter 1,3-bis(4-sulfobutyl)-1H-imidazol-3-ium hydrogen sulfate could be conveniently recycled and reused with the same efficacies for at least four cycles.
Ligand-free Suzuki-Miyaura Cross-Coupling Reactions of Aryltriazenes with Arylboronic Acids
作者:Guangming Nan、Fanghua Zhu、Zhijun Wei
DOI:10.1002/cjoc.201190063
日期:2011.1
AbstractThe boron trifluoride induced Suzuki‐Miyaura cross‐coupling of aryltriazenes with arylboronic acids catalyzed by Pd(OAc)2 without added ligands has been achieved for the first time. The reactions performed at room temperature under an argon atmosphere give biaryls in good to excellent yields. It is noteworthy that the reactions were conducted under mild and ligand‐free conditions.