[(1,2-bis(diphenylphosphino)ethane)Pt(SC6F4H-4)2] | 515843-01-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(1,2-bis(diphenylphosphino)ethane)Pt(SC6F4H-4)2]
• 英文别名: [(1,2-bis(diphenylphosphino)ethane)Pt(SC₆F₄H-4)₂]；[(dppe)Pt(SC₆F₄H-4)₂]；[(dppe)Pt(SC6F4H-4)2]；cis-[Pt(2,3,5,6-tetrafluorobenzenethiolate)2(1,2-bis(diphenylphosphino)ethane)]；[platinum(II)(p-SC6HF4)2(dppe)]；[Pt(p-SC6F4H)2(dppe)]
• CAS: 515843-01-3
• 化学式: C₃₈H₂₆F₈P₂PtS₂
• 分子量: 955.771
• InChiKey: PWQFZKONOMDWSX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  9.55
• 重原子数：
  51.0
• 可旋转键数：
  8.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  cis-[Pd(pentafluorophenyl)2(THF)2] 、 [(1,2-bis(diphenylphosphino)ethane)Pt(SC6F4H-4)2] 以 二氯甲烷 为溶剂， 以54%的产率得到[(pentafluorophenyl)2Pd(μ-2,3,5,6-tetrafluorobenzenethiolate)2Pt(1,2-bis(diphenylphosphino)ethane)]
  参考文献：
  名称：

  合成第10组多氟硫氰酸酯单核和双核配合物。[镍（SC的晶体结构6 HF 4）2（DPPE）]，[（DPPE）的Ni（μ-SC 6 HF 4）2的Pd（C 6 ˚F 5）2 ]和[（DPPE）的Ni（μ-SC 6 F 5）2 Pd（C 6 F 5）2 ]

  摘要：

  通式cis- [M（2,3,5,6-SC 6 HF 4）2（LL）]的配合物（M = Ni，Pd，Pt; L = L = dppm [双（二苯基膦基）甲烷]，通过相应的顺式[[MCl 2（LL）]]与Tl（SC ）之间的反应（1：2）合成了dppe [1,2-双（二苯基二膦基乙烷）乙烷]（收率> 75％）。6 HF 4）。这些化合物在用顺式-[M（C 6 F 5）2（THF）2 ]处理时（M = Pd，Pt; THF = OC 4 H 8），定量产生同核或异核化合物（包括两对配位异构体）。所有这些均已通过IR，NMR和质谱进行了表征。[镍（SC的晶体结构6 HF 4）2（DPPE）]，[（DPPE）的Ni（μ-SC 6 HF 4）2的Pd（C 6 ˚F 5）2 ]和[（DPPE）的Ni（μ- SC 6 F 5）2 Pd（C 6 F 5）2已经确定，并分析了芳环之间不同的界面π-π相互作用，这取决于多氟硫醇盐环的性质。

  DOI：

  10.1016/s0022-328x(02)01734-5
• 作为产物：
  描述：

  [platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)] 、 2,3,5,6-四氟苯硫酚 在 potassium tert-butylate 作用下， 以 丙酮 为溶剂， 反应 5.0h， 以83%的产率得到[(1,2-bis(diphenylphosphino)ethane)Pt(SC6F4H-4)2]
  参考文献：
  名称：

  带有SC 6 F 4 H-4配体的铂配合物–合成，结构和光谱

  摘要：

  HSC 6 F 4 H-4和碱与合适的氯化铂（II）前体复合物反应，生成含有二亚胺配体[（N ^ N）Pt（SC 6 F 4 H-4）2 ]或[[ N ^ N）Pt（Me）（SC 6 F 4 H-4）]（N ^ N = 2,2'-联吡啶（bpy），双吡啶[3,2- a：2'，3'- c ]吩嗪（dppz）或11-三氟甲基-二吡啶并[3,2- a：2'，3'- c ]吩嗪（CF 3 dppz）），环辛-1,5-二烯（COD）络合物[（COD）Pt（SC 6 F 4 H-4）2 ]或[（COD）Pt（R）（SC 6 F 4H-4）]（R = Me，Bn（苄基）或C 6 F 5）或膦络合物顺式-[（（PPh 3）2 Pt（SC 6 F 4 H-4）2 ]，[（dppe）Pt （SC 6 F 4 H-4）2 ]（dppe = 1,2-双（二苯基膦基）乙烷）和[（dppb）Pt（C 6 F 5）（SC

  DOI：

  10.1016/j.ica.2014.07.058

文献信息

• Mono- and bimetallic platinum(II) and palladium(II) complexes containing fluorinated benzothiolates
  作者：Guillermina Rivera、Sylvain Bernès、Hugo Torrens

  DOI：10.1016/j.poly.2007.05.025

  日期：2007.9

  The new mononuclear palladium(II) and platinum(II) [M(p-SC6F4(CF3))(2)(dppe)] complexes M = Pd la, Pt 2a; [M(o-SC6H4(CF3))(2)(dppe)] M = Pd Id, Pt 2d as well as the previously known [M(SC6F5)(2)(dppe)] M = Pd 1b, Pt 2b and [M(P-SC6HF4)(2)(dppe)] M = Pd 1c, Pt 2c, have been used as metalloligands for the preparation of the heteroleptic bimetallic complexes [M-2(mu-SRf)(2)(dppe)(2)](SO3CF3)(2) M = Pd, Rf = p-C6F4(CF3) 3a, C6F5 3b, p-C6HF4 3c, o-C6H4(CF3) 3d; M = Pt, Rf = p-C6F4(CF3) 4a, C6F5 4b, p-C6HF4 4c and o-C6H4(CF3) 4d. Variable temperature F-19 NMR experiments show that the fluorothiolate bridged bimetallic compounds are fluxional in solution whereas mononuclear complexes are not. The solid state X-ray diffraction structures of [Pd(p-SC6HF4)(2)(dppe)] (1c), [Pt(SC6F5)(2)(dppe)] (2b) and [Pt(o-SC6H4(CF3))(2)(dppe)] (2d) show square-planar coordination around the metal centers. The solid state molecular structure of the compound [Pt-2(mu-o-SC6H4(CF3))(2)(dppe)(2)](SO3CF3)(2) (4d), exhibit a planar [Pt-2(mu-S)(2)] ring with the sulfur substituents in an anti configuration. (c) 2007 Elsevier Ltd. All rights reserved.
• Heterobimetallic platinum(II)–palladium(II) complexes bridged by fluorobenzenethiolates. Structure and equilibria
  作者：Guillermina Rivera、Sylvain Bernès、Cecilia Rodríguez de Barbarín、Hugo Torrens

  DOI：10.1016/j.ica.2009.07.036

  日期：2009.11

  Synthesis of the heterobimetallic platinum(II)-palladium(II) complexes with poly fluorinated benzenethiolates as intermetallic bridges, [(dppe) Pd(mu-SR(F))(2)Pt(dppe)](SO(3)CF(3))(2) with SR(F) = p-SC(6)F(4)(CF(3)) (1), SC(6)F(5) (2), p-SC(6)HF(4) (3) and o-SC(6)H(4)(CF(3)) (4), have been accomplished either by a redistribution reaction in mixtures of the homonuclear bimetallic species, [(dppe) Pd(mu-SR(F))(2)Pd(dppe)](2+)/[(dppe) Pt(mu-SRF)(2)Pt(dppe)](2+) or by assembling the monometallic building blocks [(dppe) M(mu-SRF)(2)]/[(dppe)M' (solvent)(2)](2+), M, M' = Pd or Pt. Both experimental systems reach an equilibrium state which is independent of the temperature within the probed range, -90 degrees C to + 50 degrees C. A single crystal of the heterobimetallic compound [(dppe)Pd(mu-SC(6)F(5))(2)Pt(dppe)](SO(3)CF(3))(2)(acetone)(2) (2) was isolated and analyzed by X-ray diffraction. Comparison with the corresponding structures exhibited by the homobimetallic analogous, [Pd(2)(mu-SC(6)F(5))(2)(dppe)(2)](SO(3)CF(3))(2)(acetone)(2) (5) and [Pt(2)(mu-SC(6)F(5))(2)(dppe)(2)](SO(3)CF(3))(2)(acetone)(2) (6) shows that all three structures are isostructural in space group P (1) over bar. All three compounds exhibit a centrosymmetric planar [M(2)(mu-S)(2)] ring in which the sulfur substituents are arranged in an anti configuration. (C) 2009 Elsevier B. V. All rights reserved.