Zn(N,N'-bis(3-methoxysalicylidene)-1,2-diaminoethane(-2H))(H2O) | 1201160-45-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: Zn(N,N'-bis(3-methoxysalicylidene)-1,2-diaminoethane(-2H))(H2O)
• CAS: 1201160-45-3
• 化学式: C₁₈H₁₈N₂O₄*H₂O*Zn
• 分子量: 409.757
• InChiKey: CRJGQNOIBQOEIR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  0.56
• 重原子数：
  26.0
• 可旋转键数：
  7.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  120.8
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  dysprosium(III) nitrate hexahydrate 、 Zn(N,N'-bis(3-methoxysalicylidene)-1,2-diaminoethane(-2H))(H2O) 以 乙腈 为溶剂， 以68%的产率得到[Zn(NO3)(N,N'-bis(3-methoxysalicylidene)-1,2-diaminoethane(-2H))Dy(NO3)2(H2O)]
  参考文献：
  名称：

  Study of the influence of magnetic dilution over relaxation processes in a Zn/Dy single-ion magnet by correlation between luminescence and magnetism

  摘要：

  我们研究了磁稀释对荧光镝（III）/钇（III）基单离子磁体（SIM）中弛豫机制和能垒估计的影响。

  DOI：

  10.1039/c6ra24115h
• 作为产物：
  描述：

  N,N'-bis(3-methoxysalicylidene)ethylenediamine 、 zinc(II) acetate dihydrate 以 乙醇 为溶剂， 生成 Zn(N,N'-bis(3-methoxysalicylidene)-1,2-diaminoethane(-2H))(H2O)
  参考文献：
  名称：

  A bifunctional luminescent single-ion magnet: towards correlation between luminescence studies and magnetic slow relaxation processes

  摘要：

  一种新的异双核 [Zn(L)Dy]3+ 络合物，其中 L 是隔室席夫碱配体，表现出与单离子场诱导的磁化缓慢弛豫相关的特征性 Dy3+ 发光。这种复合物可以被认为是双功能发光单离子磁体的罕见例子之一。

  DOI：

  10.1039/c2cc35321k

文献信息

• Complexation of a Schiff base ligand having two coordination sites (N2O2 and O2O2) with lanthanide ions (Ln = La, Pr): an NMR study
  作者：Jean-Pierre Costes、Jean-Pierre Laussac、Franck Nicodème

  DOI：10.1039/b201136k

  日期：2002.6.27

  With the help of spectroscopic data, we have characterized several isolated entities resulting from the reaction of lanthanide ions with a hexadentate Schiff base ligand obtained by reacting o-vanillin and 1,2-diaminoethane. This H2L ligand possesses two coordination sites, an N2O2 inner site and an O2O2 outer site. In the first isolated complex, formulated as (H2L)Pr(NO3)3·H2O 1Pr, the NMR data confirm that the Pr3+ ion is only linked to the ligand by its deprotonated phenol functions while the ligand does exist in a neutral zwitterionic phenolato-iminium form (O−, NH+) in agreement with a migration of the protons from the phenolic functions to the imine groups. Deprotonation of the ligand in 1Pr yields a new and original product, LPr(NO3)·H2O·CH3OH 2Pr for which spectroscopic results agree with a coordination of the Pr3+ ion at the N2O2 site. This result, which is surprising in view of the oxophilic character of the lanthanide ions, is also confirmed by comparison with the NMR data of the LZnPr(NO3)3 complex 3Pr that retains the Pr3+ ion in the O2O2 site. Another anionic complex 4Pr, L2PrCs, with two ligands linked to the lanthanide centre by their N2O2 sites is also isolated. Starting with the mononuclear cationic or anionic entities, 2Pr or 4Pr, we have not been able to isolate and characterize genuine homo- or hetero-dinuclear lanthanide complexes.

  在光谱数据的帮助下，我们对由镧系离子与通过反应香草醛和1,2-二氨基乙烷获得的六齿式施夫碱配体反应所产生的几种孤立实体进行了表征。该H2L配体具有两个配位位点，一个是N2O2内位点，另一个是O2O2外位点。在第一个孤立的配合物中，命名为(H2L)Pr(NO3)3·H2O 1Pr，NMR数据确认Pr3+离子仅通过去质子化的酚官能团与配体相连，同时配体确实以中性内盐酚基-亚胺形式存在（O−, NH+），这与质子从酚官能团迁移到亚胺基团的现象一致。在1Pr中，配体的去质子化生成了一种新颖的产物 LPr( )· ·CH3OH 2Pr，光谱结果表明Pr3+离子在 位点配位。考虑到镧系离子的亲氧性，这一结果令我们感到惊讶，同时通过与保留Pr3+离子在O2O2位点的LZnPr( )3复合物3Pr的NMR数据进行比较也得到了验证。另一个阴离子复合物4Pr，L2PrCs，具有两个配体通过其 位点与镧系中心相连也被孤立。从单核阳离子或阴离子实体2Pr或4Pr出发，我们未能孤立和表征真正的同种或异种双核镧系配合物。
• Both magnetic relaxation and luminescence of Zn₂Dy₂ cluster complexes regulated by the bis-imine chain in Schiff base ligands
  作者：Cai-Ming Liu、De-Qing Zhang、Yi-Quan Zhang、Miao Li、Dao-Ben Zhu

  DOI：10.1039/c9nj03659h

  日期：——

  The bis-imine bridge in Schiff base ligands has effects on the magnetic relaxation and luminescence of two Zn₂Dy₂ cluster complexes.

  带有双亚胺桥的Schiff碱配体对两种Zn2Dy2簇合物的磁弛豫和发光产生影响。