2-phenoxydecane | 82971-16-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-phenoxydecane
• 英文别名: decan-2-yloxybenzene
• CAS: 82971-16-2
• 化学式: C₁₆H₂₆O
• 分子量: 234.382
• InChiKey: KXONIMNSDFBFLS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  17
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-decanone tosylhydrazone 在 mercury(II) diacetate 、 diborane(6) 作用下， 反应 17.0h， 生成 2-phenoxydecane
  参考文献：
  名称：

  N-烷基-N'-甲苯磺酰肼被Hg（OAc）2氧化。醚的新合成

  摘要：

  在醇或苯酚的存在下，带有Hg（OAc）2的N-烷基-N'-甲苯磺酰肼的收率很高。还检查了在乙酸存在下的反应。

  DOI：

  10.1016/0040-4020(82)80068-9

文献信息

• Method for foam emplacement in carbon dioxide enhanced recovery
  申请人：UNION OIL COMPANY OF CALIFORNIA

  公开号：EP0305612A1

  公开（公告）日：1989-03-08

  The permeability of higher permeability zones of a subterranean reservoir of heterogeneous permea­bility is reduced by injecting an aqueous solution of a water soluble surface active agent and then a gas mixture comprising carbon dioxide and a nonconden­sible, non-hydrocarbon gas insoluble in viscous crude. A stable foam forms in situ useful for blocking escape of solvent fluids into the higher permeability zones of the reservoir during enhanced recovery, typically by carbon dioxide flooding. Preferably, the solution of surface active agent and the gas mixture are injected in alternating slugs to enhance foam formation.

  通过注入水溶性表面活性剂的水溶液，然后注入由二氧化碳和不凝结、不溶于粘性原油的非烃类气体组成的混合气体，降低异质渗透性地下储层高渗透区的渗透率。在提高采收率的过程中，通常通过二氧化碳充注，在原地形成稳定的泡沫，用于阻止溶剂流体逸出，进入储层的高渗透区。最好是交替注入表面活性剂溶液和混合气体，以增强泡沫的形成。
• Method for producing an aromatic compound having an alkyl group with at least three carbon atoms
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP0985649A2

  公开（公告）日：2000-03-15

  Aromatic compounds having an alkyl group with at least 3 carbon atoms are produced in a process comprising at least one of the following steps: (1) a step of contacting a starting material that contains an aromatic compound having a branched alkyl group with at least 3 carbon atoms, with a zeolite-containing catalyst in a liquid phase in the presence of hydrogen therein, thereby changing the position of the carbon atoms of the alkyl group bonding to the aromatic ring of the compound; (2) a step of contacting a starting material that contains an aromatic compound having a branched alkyl group with at least 3 carbon atoms, with a catalyst containing zeolite and containing rhenium and/or silver, in a liquid phase, thereby changing the position of the carbon atoms of the alkyl group bonding to the aromatic ring of the compound; (3) a step of contacting a halogenated aromatic compound having an alkyl group with at least 3 carbon atoms, with an acid-type catalyst, thereby isomerizing the compound; and (4) a step of treating a mixture of isomers of an aromatic compound having an alkyl group with at least 3 carbon atoms, with a zeolite adsorbent that contains at least one exchangable cation selected from alkali metals, alkaline earth metals, lead, thallium and silver, thereby separating a specific isomer from the isomer mixture through adsorption.

  具有至少 3 个碳原子烷基的芳香族化合物的生产工艺至少包括以下一个步骤： (1) 将含有至少 3 个碳原子的支链烷基的芳香族化合物的起始原料在液相中与含沸石的催化剂在氢存在的情况下接触，从而改变烷基的碳原子与化合物的芳香环键合的位置； (2) 将含有芳香族化合物的起始原料与含沸石和含铼和/或银的催化剂在液相中接触，该芳香族化合物具有至少 3 个碳原子的支链烷基，从而改变烷基碳原子与化合物芳香环键合的位置； (3) 将具有至少 3 个碳原子的烷基的卤代芳香族化合物与酸型催化剂接触，从而使该化合物异构化；以及 (4) 用沸石吸附剂处理具有至少 3 个碳原子的烷基的芳香族化合物的异构体混合物，该沸石吸附剂含有至少一种选自碱金属、碱土金属、铅、铊和银的可交换阳离子，从而通过吸附从异构体混合物中分离出特定的异构体。
• GASPARRINI, F.;CAGLIOTI, L.;MISITI, D.;PALMIERI, G.;BALLINI, R., TETRAHEDRON, 1982, 38, N 24, 3609-3613
  作者：GASPARRINI, F.、CAGLIOTI, L.、MISITI, D.、PALMIERI, G.、BALLINI, R.

  DOI：——

  日期：——
• US6462248B1
  申请人：——

  公开号：US6462248B1

  公开（公告）日：2002-10-08
• Oxidation of N-alkyl-N′-tosylhydrazines with Hg(OAc)2. A new synthesis of ethers
  作者：F. Gasparrini、L. Caglioti、D. Misiti、G. Palmieri、R. Ballini

  DOI：10.1016/0040-4020(82)80068-9

  日期：1982.1

  N-Alkyl-N′-tosylhydrazines with Hg(OAc)2 in the presence of alcohols or phenol give high yields of corresponding ethers. Reactions in the presence of acetic acid are also examined.

  在醇或苯酚的存在下，带有Hg（OAc）2的N-烷基-N'-甲苯磺酰肼的收率很高。还检查了在乙酸存在下的反应。