[Dy(D-camphorato)(HCOO)] | 1451045-48-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: [Dy(D-camphorato)(HCOO)]
• 英文别名: [Dy(HCOO)(D-camphorate)]；[Dy(D-cam)(HCOO)]；[Dy(HCOO)(D-cam)]
• CAS: 1451045-48-9
• 化学式: CHO₂*C₁₀H₁₄O₄*Dy
• 分子量: 405.736
• InChiKey: LRCMBCZANXXXQW-YJGIZBEXSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -2.71
• 重原子数：
  18.0
• 可旋转键数：
  2.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  120.39
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  甲酸 、 dysprosium(III) nitrate hexahydrate 、 D-樟脑酸 以 N,N-二甲基乙酰胺 、 水 为溶剂， 反应 72.0h， 以37.92%的产率得到[Dy(D-camphorato)(HCOO)]
  参考文献：
  名称：

  Size-Selective Crystallization of Homochiral Camphorate Metal–Organic Frameworks for Lanthanide Separation

  摘要：

  Lanthanides (Ln) are a group of important elements usually found in nature as mixtures. Their separation is essential for technological applications but is made challenging by their subtly different properties. Here we report that crystallization of homochiral camphorate metalorganic frameworks (MOFs) is highly sensitive to ionic radii of lanthanides and can be used to selectively crystallize a lanthanide element into predesigned MOFs. Two series of camphorate MOFs were synthesized with acetate (Type 1 with early lanthanides LaDy) or formate (Type 2 with late lanthanides TbLu and Y) as the auxiliary ligand, respectively. The Ln coordination environment in each type exhibits selectivity for Ln(3+) of different sizes, which could form the basis for a new cost-effective method for Ln separation.

  DOI：

  10.1021/ja5067306

文献信息

• Homochiral 3D lanthanide camphorates with high thermal stability
  作者：Ming-Ling Sun、Xin Zhang、Yuan-Yuan Huang、Qi-Pu Lin、Ye-Yan Qin、Yuan-Gen Yao

  DOI：10.1039/c3nj00981e

  日期：——

  Three isomorphous homochiral 3D lanthanide coordination polymers ([Ln(HCOO)(D-cam)]n, where Ln = Dy (1), Ho (2), Er (3)), featuring sra topology have been constructed from triple-strand helical Ln–O}n rod SBUs and chiral D-cam spacers. Thermogravimetric analyses show the remarkable thermal stabilities of all three rigid lanthanide camphorate frameworks up to 450 °C.

  由三股螺旋Ln-O}n棒状SBU和手性D-cam间隔物构建了具有sra拓扑结构的三个同构的手性3D镧系元素配位聚合物（[Ln(HCOO)(D-cam)]n，其中Ln = Dy (1)、Ho (2)、Er (3)）。热重分析表明，所有三个刚性镧系樟脑酸盐骨架在450°C以下都具有卓越的热稳定性。