iron(II) meso-mono-4-pyridyltriphenylporphyrinate | 404384-04-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: iron(II) meso-mono-4-pyridyltriphenylporphyrinate
• 英文别名: meso-mono-4-pyridyltriphenylporphyrinatoiron(II)
• CAS: 404384-04-9
• 化学式: C₄₃H₂₇FeN₅
• 分子量: 669.568
• InChiKey: SFNKTRLIXKMINX-JYPWQSNKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  iron(II) meso-mono-4-pyridyltriphenylporphyrinate 、 carbon monoxide 以 neat (no solvent) 为溶剂， 生成 iron(II) meso-mono-4-pyridyltriphenylporphyrinate*2C(18)O
  参考文献：
  名称：

  摘要：

  Interaction of CO with sublimed layers of iron(II) meso-mono-4-pyridyltriphenylporphyrinate (FeM4PyTPP) resulting in the formation of known mono- and dicarbonyl complexes was studied using IR spectroscopy. The frequency of the stretching vibration of the coordinated CO in the monocarbonyl complex was found to be similar to 20 cm(-1) higher than in the complex with iron meso-tetraphenylporphyrinate (FeTPP), with the former complex being significantly more stable than the latter. The differences observed in CO coordination by porphyrins with close structures are explained by the formation, in the FeM4PyTPP sublimed layers, of oligomeric structures where the pyridyl group of one molecule is coordinated by the metal ion of the neighboring molecule. This conclusion is confirmed by a comparative analysis of IR spectra of FeM4PyTPP and FeTPP in the regions of structurally sensitive vibrations.

  DOI：

  10.1023/a:1013009011699
• 作为产物：
  描述：

  iron(II) meso-mono-4-pyridiltriphenylporphyrinate dipiperidine complex 以 solid 为溶剂， 生成 iron(II) meso-mono-4-pyridyltriphenylporphyrinate
  参考文献：
  名称：

  摘要：

  Interaction of CO with sublimed layers of iron(II) meso-mono-4-pyridyltriphenylporphyrinate (FeM4PyTPP) resulting in the formation of known mono- and dicarbonyl complexes was studied using IR spectroscopy. The frequency of the stretching vibration of the coordinated CO in the monocarbonyl complex was found to be similar to 20 cm(-1) higher than in the complex with iron meso-tetraphenylporphyrinate (FeTPP), with the former complex being significantly more stable than the latter. The differences observed in CO coordination by porphyrins with close structures are explained by the formation, in the FeM4PyTPP sublimed layers, of oligomeric structures where the pyridyl group of one molecule is coordinated by the metal ion of the neighboring molecule. This conclusion is confirmed by a comparative analysis of IR spectra of FeM4PyTPP and FeTPP in the regions of structurally sensitive vibrations.

  DOI：

  10.1023/a:1013009011699

文献信息

• ——
  作者：T. S. Kurtikyan

  DOI：10.1023/a:1024086211505

  日期：——

  IR studies revealed that unlike iron(II) meso-tetraphenylporphyrinate (FeTPP), NO interacts with sublimed layers of iron(II) meso-mono-4-pyridyltriphenylporphyrinate (FeM4PyTPP) to give two types of nitrosyl complexes. The stretching vibration frequency of the coordinated NO in one of them is close to that observed in the nitrosyl FeTPP complex, while in the other complex, it is 28 cm(-1) lower. The spectral differences observed upon coordination of NO by two porphyrins with similar structures are explained by the fact that in the sublimed FeM4PyTPP layers, the structures are formed in which the pyridyl group of one molecule is coordinated by the metal ion of the neighboring molecule, while the nitrosyl ligand occupies the sixth coordination site. The thermal stability of the complexes formed, the effect of the extra ligands on the layer structure, and the mechanism of the nitrosyl ligand exchange for its isotopic analog (NO)-N-15 are discussed.
• ——
  作者：T. S. Kurtikyan

  DOI：10.1023/a:1023415001180

  日期：——

  Low-temperature (T = 80 K) interaction of the sublimed layers of meso-mono-4-pyridyltriphenylporphyrinatoiron(II) (FeMPyTPP) with dioxygen was studied by IR and electronic absorption spectroscopies. Unlike the meso-tetraphenylporphyrinatoiron(II) (FeTPP) layers, coordination of O-2 with FeMPyTPP produces extra-complexes of two types: in the first complex one of the axial sites is free, while in the second complex an axial site is occupied by the pyridine group of the adjacent molecule. The results obtained indicate self-assembly of the FeMPyTPP molecules through coordination bonds between the iron atom and pyridine group of the adjacent molecule in the layer. The bonding of O-2 by the sublimed FeMPyTPP layers differs substantially from that by the FeTPP layers, which rapidly loose their ability of oxygen bonding at room temperature.