Amino-acetic acid (3R,4S,5R,6R)-2,3,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-4-yl ester | 46495-51-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Amino-acetic acid (3R,4S,5R,6R)-2,3,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-4-yl ester
• CAS: 46495-51-6
• 化学式: C₈H₁₅NO₇
• 分子量: 237.21
• InChiKey: UYKPBUPZSOFNIB-BCGGOHGTSA-N

反应信息

• 作为产物：
  描述：

  3-O-(N-Benzyloxycarbonyl-glycyl)-D-glucose 在 palladium on barium sulfate 氢气 作用下， 以 甲醇 、 水 为溶剂， 生成 Amino-acetic acid (3R,4S,5R,6R)-2,3,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-4-yl ester
  参考文献：
  名称：

  Glycopeptides Communication 14. Synthesis of O-(Amino-Acyl) derivatives of arabinose and mannitol

  摘要：

  DOI：

  10.1007/bf00848708

文献信息

• Amino Acid-Carbohydrate Coordinated Compounds. II. The Synthesis and the Stability of 3-<i>O</i>-Aminoacyl-D-glucoses
  作者：Nobutoshi Muramatsu

  DOI：10.1246/bcsj.39.1273

  日期：1966.6

  3-O-Aminoacyl-D-glucoses (amino acids; Gly, L-Ala, L-Lys, L-Asp (α and β) and L-Glu (α and γ)) have been prepared by the condensation of 1,2; 5,6-di-O-isopropylidene-D-glucose with suitably protected amino acid derivatives in the presence of N,N′-dicyclohexylcarbodiimide, followed by the removal of the protected groups. The effect of free amino and carboxyl groups on the stability of these compounds

  3-O-氨基酰基-D-葡萄糖（氨基酸；Gly、L-Ala、L-Lys、L-Asp（α 和 β）和 L-Glu（α 和 γ））已通过 1、 2; 5,6-二-O-异亚丙基-D-葡萄糖在N,N'-二环己基碳二亚胺存在下具有适当保护的氨基酸衍生物，然后去除保护基团。游离氨基和羧基对这些化合物稳定性的影响已得到阐明。