| 1349054-41-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• CAS: 1349054-41-6
• 化学式: C₉H₁₆O₅
• 分子量: 204.223
• InChiKey: FDEMCGVZNICXSE-NKWVEPMBSA-N

反应信息

• 作为产物：
  描述：

  methyl (2R,4S)-2-methoxy-4-methyl-6-oxohexanoate 在 氧气 作用下， 生成
  参考文献：
  名称：

  Synthesis of the C1–C20 and C15–C27 Segments of Aplyronine A

  摘要：

  The synthesis of C1-C20 and C15-C27 segments of Aplyronine A is described. Oxidative cleavage of cyclic vinyl sulfones has been used to prepare key fragments of Aplyronine A. Key precursors are united by Horner-Wadsworth-Emmons and Julia-Kociensky olefination for the respective elaboration of the C1-C20 and C15-C27 segments.

  DOI：

  10.1021/ol2024746