2,2-tetramethylenebis(3,1-benzooxaazin-4-one) | 22437-89-4

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 2,2-tetramethylenebis(3,1-benzooxaazin-4-one)
• 英文别名: 2,2'-tetramethylenebis(3,1-benzoxazin-4-one)；2-[4-(4-Oxo-3,1-benzoxazin-2-yl)butyl]-3,1-benzoxazin-4-one
• CAS: 22437-89-4
• 化学式: C₂₀H₁₆N₂O₄
• 分子量: 348.358
• InChiKey: IQDGOCFFOPHWLN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  26
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  77.3
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  邻氨基苯甲酸 生成 2,2-tetramethylenebis(3,1-benzooxaazin-4-one)
  参考文献：
  名称：

  INADA, XIROO;MATSUMURA, SYUNITI

  摘要：

  DOI：

文献信息

• Low color, low sodium benzoxazinone UV absorbers and process for making same
  申请人：——

  公开号：US20030096889A1

  公开（公告）日：2003-05-22

  The present invention relates to benzoxazinone compounds having a yellow index less than about 0, and a sodium concentration less than about 50 ppm. This invention also relates to a process for preparing these compounds comprising the step of reacting an isatoic anhydride with approximately stoichiometric amounts of an acylating compound, where the isatoic anhydride is purified by re-crystallization or other purification methods.

  本发明涉及具有黄指数小于约0和钠浓度小于约50 ppm的苯并噁唑酮化合物。本发明还涉及一种制备这些化合物的方法，包括将异恶唑酸酐与大约化学计量量的酰化化合物反应的步骤，其中异恶唑酸酐通过重结晶或其他纯化方法纯化。
• Certain polyester compositions which comprise cyclohexanedimethanol, moderate cyclobutanediol, cyclohexanedimethanol, and high trans cyclohexanedicarboxylic acid
  申请人：Moody Leslie Shane

  公开号：US20070232779A1

  公开（公告）日：2007-10-04

  Described as one aspect of the invention are polyester compositions A polyester composition comprising at least one polyester which comprises: (A) a dicarboxylic acid component comprising: i) 70 to 100 mole % of cyclohexanedicarboxylic acid residues or an ester thereof comprising: (a) 80 to 99 mole % trans-cyclohexanedicarboxylic acid residues or an ester thereof; and (b) 1 to 20 mole % cis-cyclohexanedicarboxylic acid residues or an ester thereof; ii) 0 to 30 mole % of aliphatic dicarboxylic acid residues, other than cyclohexanedicarboxylic acid residues, having up to 16 carbon atoms or esters thereof, other than cyclohexanedicarboxylic acid residues; and iii) 0 to 10 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and (B) a glycol component comprising: i) 5 to 35 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and ii) 65 to 95 mole % of 1,4-cyclohexanedimethanol residues, 1,3-cyclohexanedimethanol residues, 1,2-cyclohexanedimethanol residues or esters thereof or mixtures thereof, wherein the total mole % of said dicarboxylic acid component is equal to 100 mole %; the total mole % of said glycol component is equal to 100 mole %; wherein the inherent viscosity of said polyester is from 0.35 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C.; and wherein said polyester has a Tg of from 66 to 120° C. The polyesters may be manufactured into articles.

  本发明的一方面是聚酯组合物，其中包括至少一种聚酯，该聚酯包括：(A) 二羧酸组分，包括：i) 70至100摩尔％的环己二甲酸残基或其酯，包括：(a) 80至99摩尔％的反式环己二甲酸残基或其酯；和(b) 1至20摩尔％的顺式环己二甲酸残基或其酯；ii) 0至30摩尔％的具有高达16个碳原子的脂肪族二羧酸残基（环己二甲酸残基除外）或其酯；以及iii) 0至10摩尔％的具有高达20个碳原子的芳香族二羧酸残基；和(B) 二元醇组分，包括：i) 5至35摩尔％的2,2,4,4-四甲基-1,3-环丁二醇残基；和ii) 65至95摩尔％的1,4-环己二甲醇残基，1,3-环己二甲醇残基，1,2-环己二甲醇残基或其酯或其混合物，其中所述二羧酸组分的总摩尔％等于100摩尔％；所述二元醇组分的总摩尔％等于100摩尔％；其中所述聚酯的固有粘度在60/40（重量/重量）苯酚/四氯乙烷中以0.5 g / 100 ml浓度在25°C下测定为0.35至1.2 dL / g；且所述聚酯的Tg在66至120°C之间。这些聚酯可以制成物品。
• Certain polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and high trans-cyclohexanedicarboxylic acid
  申请人：Moody Leslie Shane

  公开号：US20070232778A1

  公开（公告）日：2007-10-04

  Described as one aspect of the invention are polyester compositions comprising at least one polyester which comprises: (A) a dicarboxylic acid component comprising: i) 70 to 100 mole % of cyclohexanedicarboxylic acid residues or an ester thereof comprising: (a) 70 to 98 mole % trans-cyclohexanedicarboxylic acid residues or an ester thereof; and (b) 2 to 30 mole % cis-cyclohexanedicarboxylic acid residues or an ester thereof; ii) 0 to 30 mole % of aliphatic dicarboxylic acid residues, other than cyclohexanedicarboxylic acid residues, having up to 16 carbon atoms or esters thereof, other than cyclohexanedicarboxylic acid residues,; and iii) 0 to 10 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and (B) a glycol component comprising: i) 1 to 99 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and ii) 1 to 99 mole % of 1,4-cyclohexanedimethanol residues, 1,3-cyclohexanedimethanol residues, 1,2-cyclohexanedimethanol residues or esters thereof or mixtures thereof, wherein the total mole % of said dicarboxylic acid component is equal to 100 mole %; the total mole % of said glycol component is equal to 100 mole %; wherein the inherent viscosity of said polyester is from 0.35 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C.; and wherein said polyester has a Tg of from 60 to 155° C. The polyesters may be manufactured into articles.

  本发明的一方面是聚酯组合物，包括至少一种聚酯，其包括：（A）二羧酸成分，包括：i）70至100摩尔％的环己烷二羧酸残基或其酯，包括：（a）70至98摩尔％的反式环己烷二羧酸残基或其酯；和（b）2至30摩尔％的顺式环己烷二羧酸残基或其酯；ii）0至30摩尔％的脂肪族二羧酸残基，除了具有高达16个碳原子的环己烷二羧酸残基或其酯之外；和iii）0至10摩尔％的具有高达20个碳原子的芳香族二羧酸残基；以及（B）乙二醇成分，包括：i）2,2,4,4-四甲基-1,3-环丁二醇残基的1至99摩尔％；和ii）1,4-环己二甲醇残基、1,3-环己二甲醇残基、1,2-环己二甲醇残基或其酯或其混合物的1至99摩尔％；其中，所述二羧酸成分的总摩尔％等于100摩尔％；所述乙二醇成分的总摩尔％等于100摩尔％；其中，所述聚酯的固有粘度为0.35至1.2 dL/g，在60/40（重量/重量）苯酚/四氯乙烷中，在25°C下浓度为0.5 g/100 ml时确定；所述聚酯具有从60°C到155°C的Tg。这些聚酯可以制成物品。
• Process for producing aromatic polyesters having increased degrees of polymerization and moulded articles composed of these polyesters
  申请人：TEIJIN LIMITED

  公开号：EP0019061A1

  公开（公告）日：1980-11-26

  A process for producing an aromatic polyester having an increased degree of polymerization. The process comprises reacting a hydroxyl-terminated, substantially linear, fiber-forming aromatic polyester having an aromatic dicarboxylic acid as a main acid component at an elevated temperature with a bi-cyclic imino ester compound of formula (I) or formula (II). According to the process, the molecularchains of the aromatic polyester are bonded to each other by the terminal hydroxyl groups thereof to form rapidly the aromatic polyester having an increased degree of polymerization. I Bis-oxazolones 11 Bis-oxazinones e.g.

  一种生产聚合度提高的芳香族聚酯的工艺。该工艺包括在高温下使以芳香族二羧酸为主要酸组分的羟基封端、基本线性的芳香族聚酯与式 (I) 或式 (II) 的双环亚氨基酯化合物反应。根据该工艺，芳香族聚酯的分子链通过其末端羟基相互键合，从而快速形成聚合度提高的芳香族聚酯。 I 双噁唑酮 11 双噁唑酮，例如
• Flame-retardant resin composition and electric wire
  申请人：POLYPLASTICS CO. LTD.

  公开号：EP0320159A1

  公开（公告）日：1989-06-14

  The invention provides a flame-retardant resin composition characterised in that it comprises (A) an aromatic polyester prepared by condensation polymerization between (a) a component substantially comprising an aromatic dicarboxylic acid or an ester-­forming derivative thereof and (b) a component substantially comprising an aliphatic diol or an ester-­forming derivative thereof, (B) 0.1 to 30% by weight based on the total amount of the composition of a compound represented by the general formula (1) or (2) wherein X represents a halogen atom; Y₁ and Y₂ each represent a group selected from hydroxyl, carboxyl, glycidyl ester and glycidyl ether groups; Z is a monovalent or divalent organic group and n is an integer of 1 or more and (C) 0.1 to 30% by weight based on the total amount of the composition of a compound represented by the general formula (3): L₁-M-L₂      (3) wherein M is a divalent organic group L₁ and L₂ may be the same or different from each other and each represent a 3- to 8-membered cyclic reactive group selected from those having the general formulae (4) to (7): in which each of R₁, R₂ and R₃ represent a divalent organic group wherein a hydrogen atom directly bonded to the ring may be substituted with an alkyl and/or aryl group. The invention also includes electric wires coated therewith.

  本发明提供了一种阻燃树脂组合物，其特征在于该组合物包括 (A) 由以下组分缩合聚合制备的芳香族聚酯：(a) 主要由芳香族二羧酸或其酯类衍生物组成的组分；(b) 主要由脂肪族二元醇或其酯类衍生物组成的组分、 (B) 以组合物总重量为基准，0.1%至 30%由通式(1)或(2)代表的化合物 其中 X 代表卤素原子；Y₁ 和 Y₂ 各自代表选自羟基、羧基、缩水甘油酯和缩水甘油醚基团的基团；Z 是一价或二价有机基团，n 是 1 或 1 以上的整数，且 (C) 通式（3）所代表的化合物占组合物总量的 0.1%至 30%（以重量计）： L₁-M-L₂ (3) 其中 M 是二价有机基团 L₁ 和 L₂ 可以彼此相同或不同，各自代表从通式（4）至（7）中选出的 3 至 8 元环状活性基团： 其中 R₁、R₂ 和 R₃ 各自代表二价有机基团，其中与环直接结合的氢原子可被烷基和/或芳基取代。 本发明还包括涂有该物质的电线。