2-(1-(2-aminophenylimino)ethyl)phenol | 262276-71-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(1-(2-aminophenylimino)ethyl)phenol
• 英文别名: N-(2-hydroxyacetophenone)-1-amino-2-phenyleneimine；2-[(2-hydroxyphenyl)ethylideneamino]-phenylamine；2-[1-(2-Aminophenylimino)ethyl]phenol；2-[N-(2-aminophenyl)-C-methylcarbonimidoyl]phenol
• CAS: 262276-71-1
• 化学式: C₁₄H₁₄N₂O
• 分子量: 226.278
• InChiKey: FJNFPVPQEJYLQG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  58.6
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-[(2-羟基苯基)亚甲基]戊烷-2,4-二酮 、 2-(1-(2-aminophenylimino)ethyl)phenol 以 乙醇 为溶剂， 反应 8.0h， 以75%的产率得到2,4-bis(2-[1-(2-hydroxyphenyl)ethylideneamino]phenylimino)-3-(2-hydroxybenzylidene)pentane
  参考文献：
  名称：

  Tetra- and hexadentate Schiff base ligands and their Ni(II), Cu(II) and Zn(II) complexes. Synthesis, spectral, magnetic and thermal studies

  摘要：

  Tetradentate N2O2, N-4 Schiff bases, 1,2-bis(4-oxopent-2-ylideneamino) benzene (BOAB), 1-(4-oxopent-2-ylideneamino-2-[(2-hydroxyphenynethylideneamino] benzene (OAHAB), 7,16-bis(4-chlorobenzylidene)-6,8,15,17-tetra-methyl-7,16-dihydro -5,9,14,18-tetraza-dibenzo[a,h] cyclo tetradecene (BCB-DCT), 7,16-bis(2-hydroxy-benzylidene)-6,8,15,17-tetramethyl-7,16-dihydro-5,9,14,18-tetraza-dibenzo la,h] cyclo tetradecene (BHBDCT) and hexadentate N4O2 Schiff bases, 2,4-bis {2-[1-(2-hydroxyphenyl) ethylideneamino] phenylimino}-3-(2-hydroxybenzylidene) pentane (BHAPHP), 2,4-bis {2-[1-(2hydroxyphenyl) ethylideneamino] phenylimino}-3-(4-chlorobenzylidene) pentane (BHAPCP) were prepared and characterized by elemental analysis, IR, UV Vis, H-1 NMR and mass spectra. The solid complexes of the prepared Schiff base ligands with Ni(II), Cu( II) and Zn(II) ions were isolated and characterized by elemental and thermal analyses, IR, electronic and ESR spectra as well as conductance and magnetic susceptibility measurements. The results showed that most complexes have octahedral geometry but few can attain the tetrahedral arrangement. The TG analyses suggest high stability for most complexes followed by thermal decomposition in different steps. The kinetic and thermodynamic parameters for decomposition steps in Cu(II) complexes thermograms have been calculated. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2011.10.037
• 作为产物：
  描述：

  2'-羟基苯乙酮 、 邻苯二胺 以 乙醇 为溶剂， 以60%的产率得到2-(1-(2-aminophenylimino)ethyl)phenol
  参考文献：
  名称：

  1,2-亚苯基二胺和1,3-萘二胺衍生的不对称四齿钒基席夫碱配合物作为环己烯氧化的催化剂

  摘要：

  通过模板法和非模板法合成了由苯二胺和1,3-萘二胺衍生的两个新的不对称二亚氨基四亚齿四齿席夫碱及其钒基配合物，其特征在于1 H，1313 C NMR，IR，UV-Vis和元素分析。这些络合物用作环己烯的选择性好氧氧化的催化剂。随着电子给体基团数目的减少，催化活性增加，并且通过改变配体上的取代基来改变催化选择性。本文所述的催化系统是一种高效且廉价的烯烃氧化方法，具有活性高，选择性高，可重复使用性和反应时间短的优点。含有萘桥联配体的配合物具有相似的氧化还原电势，但是它们的催化活性差异很大。它们活性的差异很大程度上取决于精细的结构数据和ΔE p。但是，在含有亚苯基桥联配体的配合物中，比较GC，氧化还原电势和ΔE p测量值可在催化活性和氧化还原电势之间产生良好的相关性，并且对选择性的影响很小。通常，转化率随着ΔE p的增加和E redox 0'的减少而降低。

  DOI：

  10.1016/s0040-4020(02)00481-7

文献信息

• CURING AGENTS FOR EPOXY RESINS
  申请人：Dershem Stephen M

  公开号：US20130012620A1

  公开（公告）日：2013-01-10

  The present invention relates to curatives for epoxy resins, and compositions (e.g. adhesives) containing such resins cured using the same methods of preparation and uses therefor. More specifically, the present invention relates to hybrid curatives for epoxy resins comprising both aromatic amine, phenol and/or phenyl ester moieties. A further aspect of the current invention relates to new imidazole catalysts that possess a combination of excellent cure latency as well as low cure temperature onset.

  本发明涉及环氧树脂的硬化剂，以及含有经相同制备方法固化的这种树脂的组合物（例如胶粘剂）及其用途。更具体地，本发明涉及用于环氧树脂的混合硬化剂，包括芳香胺、酚和/或苯酯基团。本发明的另一个方面涉及具有优异固化潜伏期和低固化温度起始点的新咪唑催化剂。
• Epoxidation of alkenes by an oxidovanadium(IV) tetradentate Schiff base complex as an efficient catalyst with tert-butyl hydroperoxide
  作者：Maryam Sedighipoor、Ali Hossein Kianfar、Wan Ahmad Kamil Mahmood、Mohammad Hossein Azarian

  DOI：10.1016/j.ica.2016.12.018

  日期：2017.3

  tetradentate N2O2 Schiff base ligand was synthesized from 2-hydroxyacetophenon, 2-hydroxynaphthaldehyde and 1,2 phenylenediimine. The new oxidovanadium(IV) Schiff base complex, VIVOL (L = N-2-hydroxyacetophenon-N′-2-hydroxynaphthaldehyde-1,2 phenylenediimine), was prepared by reaction of Schiff base ligand with vanadyl acetylacetonate. The Schiff base ligand (L) and the oxidovanadium(IV) complex were characterized

  摘要由2-羟基苯乙酮，2-羟基萘乙醛和1,2-苯二胺合成了一种新的不对称四齿N2O2席夫碱配体。通过席夫碱配体与乙酰丙酮氧钒反应，制得了新的氧化钒席夫碱络合物VIVOL（L = N-2-羟基苯乙酮-N'-2-羟基萘醛-1，2-苯二胺）。通过光谱方法表征了席夫碱配体（L）和氧化钒（IV）配合物。通过单晶X射线分析确定配合物的晶体结构。该络合物在正交晶系中结晶，具有一个V4 +离子，在一个近似正方形的金字塔N2O3几何结构中，该结构由两个甲硫氨酸N原子和来自席夫碱配体的酚氧在一个正方形平面中配位，并且一个氧原子在顶端位置。配合物的电化学性质通过循环伏安法检查。在环辛烯的环氧化中测试了氧化钒（IV）席夫碱配合物的催化活性。
• Curing agents for epoxy resins
  申请人：Designer Molecules, Inc.

  公开号：US08288591B2

  公开（公告）日：2012-10-16

  A variety of curing agents for epoxy resins and methods for preparation thereof are disclosed, including compounds having the structures of formulas III and IV: wherein each of R1, R2, R3, R4, and R5 is independently selected from the group consisting of H, methyl, ethyl, n-propyl, iso-propyl, a butyl, and phenyl. Epoxy-based compositions including various curing agents are also disclosed. Other epoxy curatives containing amino, phenol, and/or imine groups are disclosed.

  揭示了用于环氧树脂的各种固化剂以及其制备方法，包括具有III和IV式结构的化合物：其中R1、R2、R3、R4和R5中的每一个独立地选自H、甲基、乙基、正丙基、异丙基、丁基和苯基。还揭示了包括各种固化剂的基于环氧的组合物。还揭示了含有氨基、酚基和/或亚胺基固化剂。
• Synthesis, spectroscopy, electrochemistry and thermal study of vanadyl unsymmetrical Schiff base complexes
  作者：Ali Hossein Kianfar、Vida Sobhani、Morteza Dostani、Mojtaba Shamsipur、Mahmoud Roushani

  DOI：10.1016/j.ica.2010.08.041

  日期：2011.1

  tetradentate unsymmetrical N2O2 Schiff base ligands and VO(IV) complexes were synthesised and characterized by using IR, UV–Vis and elemental analysis. The electrochemical properties of the vanadyl complexes were investigated by means of cyclic voltammetry. The oxidation potentials are increased by increasing the electron-withdrawing properties of functional groups of the Schiff base ligands according to the

  合成了新的四齿不对称N 2 O 2 Schiff碱配体和VO（IV）配合物，并通过IR，UV-Vis和元素分析对其进行了表征。通过循环伏安法研究了钒基配合物的电化学性质。根据MeO
• Synthesis and characterization of non-symmetric tetradentate complexes of Zn(II), Co(II), and Cu(II)
  作者：MARYAM LASHANIZADEGAN、SHIMA SERAJ

  DOI：10.3906/kim-0811-31

  日期：——

  The non-symmetrical tetradentate Schiff-base H_2L was obtained using the half-unit N-(1-hydroxy-2-acetophenone)-1-amino- 2-phenyleneimine (HL) with 2-hydroxyl-1-naphthaldehyde. ZnL, CoL, and CuL complexes were prepared and characterized by ^1H-NMR, IR, electronic, and atomic absorption spectra. The single crystal X-ray structure of CuL was determined. Crystal data for CuL are triclinic space group P-1, a = 8.3933 (17) Å, b = 11.197 (2) Å, c = 13.381 (3) Å, \alpha = 95.29 (3)°, \beta = 94.37 (3)°, \gamma = 95.82 (3)°, and z = 2.

  利用半单位 N-（1-羟基-2-苯乙酮）-1-氨基-2-苯亚胺（HL）和 2-羟基-1-萘甲醛，得到了非对称的四价席夫碱 H_2L。 制备了 ZnL、CoL 和 CuL 复合物，并通过^1H-NMR、IR、电子和原子吸收光谱对其进行了表征。 测定了 CuL 的单晶 X 射线结构。 CuL 的晶体数据为三菱空间群 P-1，a = 8.3933 (17) Å，b = 11.197 (2) Å，c = 13.381 (3) Å，α = 95.29 (3)°，β = 94.37 (3)°，γ = 95.82 (3)°，z = 2。