bis[1-(2-chloroethyl)tetrazole]bis(nitrato)copper(II) | 619302-29-3

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: bis[1-(2-chloroethyl)tetrazole]bis(nitrato)copper(II)
• CAS: 619302-29-3
• 化学式: C₆H₁₀Cl₂CuN₁₀O₆
• 分子量: 452.661
• InChiKey: VEMXFNQMPBTDMC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  copper(II) nitrate trihydrate 、 1-(2-chloroethyl)tetrazole 以 甲醇 为溶剂， 生成 bis[1-(2-chloroethyl)tetrazole]bis(nitrato)copper(II)
  参考文献：
  名称：

  Structure and magnetic properties of the weak ferromagnet bis(1-(2-chloroethyl)-tetrazole)bis(nitrato)copper(II)

  摘要：

  The novel mononuclear complex [Cu(teec)(2)(NO3)(2)] with teec = 1-(2-chloroethyl)tetrazole, has been prepared from 1 equiv. copper(II) nitrate with 2 equiv. of teec. The X-ray structure shows the formation of a mononuclear complex with hexa-coordinated copper(II) ions. The teec ligands are positioned in trans orientation with a distorted axial geometry. Two of the Cu-O bonds of the chelating nitrate anions are significantly longer than the other two Cu-O bonds (1.99 vs. 2.48 Angstrom). Linear-chain packing of the mononuclear units is reflected in very weak, linear ferromagnetic chains with theta = 0.30 K and C = 0.44 cm(3) K mol(-1). The spectral properties are in accord with the structural and magnetic data. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01496-2