2-Oct-7-enoxypropane-1,3-diol | 957786-67-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 英文名称: 2-Oct-7-enoxypropane-1,3-diol
• 英文别名: 2-oct-7-enoxypropane-1,3-diol
• CAS: 957786-67-3
• 化学式: C₁₁H₂₂O₃
• 分子量: 202.294
• InChiKey: PVWWYXAUZSGWQD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  14
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  49.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-Oct-7-enoxypropane-1,3-diol 、 碘甲烷 在 potassium tert-butylate 作用下， 以 四氢呋喃 为溶剂， 反应 10.0h， 以54%的产率得到
  参考文献：
  名称：

  Hyperbranched Macromolecules via Olefin Metathesis

  摘要：

  A facile route to hyperbranched polymers via acyclic diene metathesis is reported. Any molecule functionalized with two or more acrylate groups and one terminal olefin can serve as an AB, monomer when exposed to an imidazolinylidene-based ruthenium olefin metathesis catalyst, due to the cross metathesis selectivity of this catalyst. For the polymers obtained by this method, both H-1 NMR spectroscopy and triple detector size exclusion chromatography conclusively indicate a branched architecture.

  DOI：

  10.1021/ja0759040
• 作为产物：
  描述：

  8-溴-1-辛烯 、 2-苯基-1,3-二氧六环-5-醇 在 potassium hydride 作用下， 以 甲苯 为溶剂， 反应 10.0h， 以53%的产率得到2-Oct-7-enoxypropane-1,3-diol
  参考文献：
  名称：

  Hyperbranched Macromolecules via Olefin Metathesis

  摘要：

  A facile route to hyperbranched polymers via acyclic diene metathesis is reported. Any molecule functionalized with two or more acrylate groups and one terminal olefin can serve as an AB, monomer when exposed to an imidazolinylidene-based ruthenium olefin metathesis catalyst, due to the cross metathesis selectivity of this catalyst. For the polymers obtained by this method, both H-1 NMR spectroscopy and triple detector size exclusion chromatography conclusively indicate a branched architecture.

  DOI：

  10.1021/ja0759040

文献信息

• Hyperbranched Macromolecules via Olefin Metathesis
  作者：Irina A. Gorodetskaya、Tae-Lim Choi、Robert H. Grubbs

  DOI：10.1021/ja0759040

  日期：2007.10.1

  A facile route to hyperbranched polymers via acyclic diene metathesis is reported. Any molecule functionalized with two or more acrylate groups and one terminal olefin can serve as an AB, monomer when exposed to an imidazolinylidene-based ruthenium olefin metathesis catalyst, due to the cross metathesis selectivity of this catalyst. For the polymers obtained by this method, both H-1 NMR spectroscopy and triple detector size exclusion chromatography conclusively indicate a branched architecture.