trans-[bis(2-salicyloylhydrazonato-1,3-dithiolane)bis(pyridine)manganese(II)] | 868568-11-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trans-[bis(2-salicyloylhydrazonato-1,3-dithiolane)bis(pyridine)manganese(II)]
• CAS: 868568-11-0
• 化学式: C₃₀H₂₈MnN₆O₄S₄
• 分子量: 719.792
• InChiKey: AAEFHPZYQJAPSH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吡啶 、 2-salicyloylhydrazono-1,3-dithiolane 、 manganous acetylacetonate 以 吡啶 、 甲醇 为溶剂， 以84%的产率得到trans-[bis(2-salicyloylhydrazonato-1,3-dithiolane)bis(pyridine)manganese(II)]
  参考文献：
  名称：

  New manganese complexes with 2-salicyloylhydrazono-1,3-dithiolane ligand and various coordination solvents

  摘要：

  The new Mn(HL)(2)L'(2) complexes with 2-salicyloylhydrazono-1,3-dithiolane ligand (H2L) have been obtained with good yields (approximate to 85%) by reacting manganese (II) acetate tetrahydrate or manganese (II) acetylacetonate with 2-salicyloylhydrazono-1,3-dithiolane ligand in DMF, THF or Py (L'). These compounds have been fully characterized by spectroscopic methods and single crystal X-ray diffraction. In the solid state, supramolecular networks are described and discussed in terms of weak H-bonds and short contacts. The new monomeric complexes will be considered as candidates to obtain polynuclear complexes. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.06.037