[Pt(1,2-bis(7-azaindolyl)benzene)Me3][OTf] | 1013645-27-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: [Pt(1,2-bis(7-azaindolyl)benzene)Me3][OTf]
• 英文别名: [Pt(BAB)Me3][OTf]；carbanide;platinum(4+);1-(2-pyrrolo[2,3-b]pyridin-1-ylphenyl)pyrrolo[2,3-b]pyridine;trifluoromethanesulfonate
• CAS: 1013645-27-6
• 化学式: CF₃O₃S*C₂₃H₂₃N₄Pt
• 分子量: 699.613
• InChiKey: BSCXUCDFAOMZFE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  5.76
• 重原子数：
  36
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  101
• 氢给体数：
  0
• 氢受体数：
  11

反应信息

• 作为反应物：
  描述：

  [Pt(1,2-bis(7-azaindolyl)benzene)Me3][OTf] 、 四丁基碘化铵 以 not given 为溶剂， 生成 {trimethylplatinum(IV) iodide}4
  参考文献：
  名称：

  Steric Impact of Neutral N,N-Chelates on the Structure and Stability of Five-Coordinate Platinum(IV) Complexes: fac-Pt^IVMe₃ Complexes of BAB and BAM

  摘要：

  Two neutral 7-azaindolyl derivative ligands, BAB and BAM, have been found to have a distinct impact on the structure and stability of five-coordinate Pt(IV)Me(3) complexes. A five-coordinate Pt(IV) complex of BAB and two six-coordinate Pt(IV) complexes of BAM have been isolated, which display distinct dynamic behavior in solution. The BAM ligand can be converted to an N,C,N-chelate that forms a stable six-coordinate Pt(IV) complex.

  DOI：

  10.1021/om701264z
• 作为产物：
  描述：

  [PtMe3OTf]4 、 1,2-bis(N-7-azaindolyl)benzene 以 四氢呋喃 为溶剂， 以74%的产率得到[Pt(1,2-bis(7-azaindolyl)benzene)Me3][OTf]
  参考文献：
  名称：

  Steric Impact of Neutral N,N-Chelates on the Structure and Stability of Five-Coordinate Platinum(IV) Complexes: fac-Pt^IVMe₃ Complexes of BAB and BAM

  摘要：

  Two neutral 7-azaindolyl derivative ligands, BAB and BAM, have been found to have a distinct impact on the structure and stability of five-coordinate Pt(IV)Me(3) complexes. A five-coordinate Pt(IV) complex of BAB and two six-coordinate Pt(IV) complexes of BAM have been isolated, which display distinct dynamic behavior in solution. The BAM ligand can be converted to an N,C,N-chelate that forms a stable six-coordinate Pt(IV) complex.

  DOI：

  10.1021/om701264z