2-(cyclohex-1-en-1-yl)-1-methyl-1H-benzimidazole | 1367707-58-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: 2-(cyclohex-1-en-1-yl)-1-methyl-1H-benzimidazole
• 英文别名: 2-(Cyclohexen-1-yl)-1-methylbenzimidazole；2-(cyclohexen-1-yl)-1-methylbenzimidazole
• CAS: 1367707-58-1
• 化学式: C₁₄H₁₆N₂
• 分子量: 212.294
• InChiKey: KHDUXKARGAFULZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  17.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  diphenyl enol phosphate of cyclohexanone 在 1,1'-双(二苯膦基)二茂铁二氯化钯(II)二氯甲烷复合物 、 碘代三甲硅烷 、 三苯基膦 、 silver carbonate 作用下， 以 二氯甲烷 、 水 为溶剂， 反应 1.0h， 生成 2-(cyclohex-1-en-1-yl)-1-methyl-1H-benzimidazole
  参考文献：
  名称：

  Palladium-catalyzed direct functionalization of benzoxazoles with alkenyl iodides

  摘要：

  A straightforward procedure for the palladium-catalyzed direct functionalization of benzoxazoles with alkenyl iodides is described. The reactions employ a Pd(II)-precatalyst and use 'on water' conditions to achieve the ready union of a range of di- and tri-substituted alkenyl iodides with a small range of benzoxazoles. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.02.014

文献信息

• ORGANIC ELECTROLUMINESCENT DEVICE AND MATERIAL FOR ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP2166587A1

  公开（公告）日：2010-03-24

  An organic electroluminescence device includes: a cathode; an anode; and a single-layered or multilayered organic thin-film layer provided between the cathode and the anode. The organic thin-film layer includes an emitting layer. The emitting layer contains a phosphorescent material and a host material represented by the following formula (1).         Ra-Ar1-Rb     (1) In the formula, Ar1, Ra and Rb each represent a substituted or unsubstituted benzene ring or a fused aromatic hydrocarbon ring selected from a substituted or unsubstituted naphthalene ring, a substituted or unsubstituted chrysene ring, a substituted or unsubstituted fluoranthene ring, a substituted or unsubstituted phenanthrene ring, a substituted or unsubstituted benzophenanthrene ring, a substituted or unsubstituted dibenzophenanthrene ring, a substituted or unsubstituted triphenylene ring, a substituted or unsubstituted benzo[a]triphenylene ring, a substituted or unsubstituted benzochrysene ring, a substituted or unsubstituted benzo[b]fluoranthene ring and a substituted or unsubstituted picene ring. Substituents for Ra and Rb are not aryl groups.

  一种有机电致发光器件包括：阴极；阳极；以及位于阴极和阳极之间的单层或多层有机薄膜层。有机薄膜层包括发光层。发光层包含磷光材料和由下式（1）表示的主材料。 Ra-Ar1-Rb (1) 式中，Ar1、Ra 和 Rb 分别代表一个取代或未取代的苯环或一个融合芳香烃环，它们选自取代或未取代的萘环、取代或未取代的菊烯环、取代或未取代的荧蒽环、取代或未取代的菲环、取代或未取代的二苯并菲环、取代或未取代的二苯并菲环、取代或未取代的三亚 苯环、取代或未取代的苯并[a]三亚苯环、取代或未取代的苯并芘环、取代或未取代的 苯并[b]荧蒽环以及取代或未取代的皮烯环。Ra 和 Rb 的取代基不是芳基。
• ORGANIC EL ELEMENT
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP2221896A1

  公开（公告）日：2010-08-25

  An organic electroluminescence device includes an anode, a cathode, and an organic thin-film layer interposed between the anode and the cathode. The organic thin-film layer includes a phosphorescent-emitting layer containing a host and a phosphorescent dopant, and an electron transporting layer that is provided closer to the cathode than the phosphorescent-emitting layer. The host contains a substituted or unsubstituted polycyclic fused aromatic skeleton.

  一种有机电致发光器件包括阳极、阴极和置于阳极与阴极之间的有机薄膜层。有机薄膜层包括一个磷光发光层，该层含有一个宿主和一个磷光掺杂剂，以及一个电子传输层，该层比磷光发光层更靠近阴极。宿主含有取代或未取代的多环融合芳香族骨架。
• Palladium-catalyzed direct functionalization of benzoxazoles with alkenyl iodides
  作者：Maria Gerelle、Anne J. Dalencon、Michael C. Willis

  DOI：10.1016/j.tetlet.2012.02.014

  日期：2012.4

  A straightforward procedure for the palladium-catalyzed direct functionalization of benzoxazoles with alkenyl iodides is described. The reactions employ a Pd(II)-precatalyst and use 'on water' conditions to achieve the ready union of a range of di- and tri-substituted alkenyl iodides with a small range of benzoxazoles. (C) 2012 Elsevier Ltd. All rights reserved.