Ag(κ2-C5H4N-CHN-CH2C6H5)(P(C6H5)3)2(CF3SO3) | 1350610-68-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: Ag(κ2-C5H4N-CHN-CH2C6H5)(P(C6H5)3)2(CF3SO3)
• CAS: 1350610-68-2
• 化学式: CF₃O₃S*C₄₉H₄₂AgN₂P₂
• 分子量: 977.772
• InChiKey: SFDMNWJDBNZYMY-WUPYCCQWSA-M

反应信息

• 作为产物：
  描述：

  N-benzyl-1-pyridin-2-ylmethanimine 、 Ag(OTf)(PPh3) 以 二氯甲烷 为溶剂， 以50%的产率得到Ag(κ2-C5H4N-CHN-CH2C6H5)(P(C6H5)3)2(CF3SO3)
  参考文献：
  名称：

  1D and 2D Nuclear magnetic resonance of new silver(I) complexes with achiral and chiral bases as ligands: Crystal structure of [Ag{(S)-(6-CH3)C5H3N-CHN-C*H(α-CH3)C6H5}(PPh3)2](O3SCF3)

  摘要：

  Treatment of equimolar amounts of substituted aniline or amine with substituted benzaldehyde leads to the corresponding achiral or chiral Schiff bases (L). The reaction of the bases with [Ag(O3SCF3)(PPh3)] leads to the preparation of three or four coordinated cationic complexes, [Ag(k(1)-L)(PPh3)(n)](+) (n = 1 or 2) which have been characterized by IR, D-1 and D-2 NMR spectroscopy. The crystal structure of [Ag{(S)-(6-CH3)C5H3N-CHN-C*H(alpha-CH3)C6H5}(PPh3)(2)](O3SCF3) is reported. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.09.033