[Pd2Cl2(sarcosine ethyl ether dithiocarbamate)2(1,7-diaminoheptane)] | 1334597-11-3

• 英文名称: [Pd2Cl2(sarcosine ethyl ether dithiocarbamate)2(1,7-diaminoheptane)]
• 英文别名: [Pd2Cl2(ESDT)2(dah)]
• CAS: 1334597-11-3
• 化学式: C₁₉H₃₈Cl₂N₄O₄Pd₂S₄
• 分子量: 798.545
• InChiKey: PBHJPYXABAXYQS-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [PdCl(sarcosine ethyl ether dithiocarbamate)] 、 四亚甲基二胺 以 二氯甲烷 、 苯 为溶剂， 以75%的产率得到[Pd2Cl2(sarcosine ethyl ether dithiocarbamate)2(1,7-diaminoheptane)]
  参考文献：
  名称：

  Synthesis, characterization and cytotoxic activity of palladium (II) dithiocarbamate complexes with α,ω-diamines

  摘要：

  The polymeric [PdCl(dithiocarbamate)](n) complexes, in which the ligand ion is dimethyldithiocarbamate (DMDT), pyrrolidine dithiocarbamate (PyDT, (CH2)(4)NCS2-) and sarcosine ethyl ester dithiocarbamate (ESDT, EtO2CCH2N(CH3)CS2-), have been reacted with chelating diamines, like ethylenediamine (en) or 1,3-diaminopropane (dap) and long chain diamines, like 1,4-diaminobutane (dab) or 1,7-diaminoheptane (dah). The reaction products depend on either diamine chain length or molar ratio. By operating at PdCl(dithiocarbamate)/diamine molar ratio 1:1 chelating diamines yielded the ionic [Pd(dithiocarbamate)(diamine)]Cl species (diamine = en or dap), whereas with long chain diamines species of the type [Pd(dithiocarbamate)(diamine)](n)Cl-n (diamine = dab or dah) were obtained, in which each Pd(dithiocarbamate)(+) unit binds to the NH2 group of two different molecules, in a network of bridging diamines. At molar ratio 1:0.5, the long chain diamines yielded the binuclear [Pd2Cl2(dithiocarbamate)(2)(diamine)] complexes (diamine = dab or dah), whereas exchange reactions take place generally in the presence of en or dap. The reaction trend is described on the basis of IR and proton NMR spectra. The new dithiocarbamate complexes were preliminarily tested for their cytotoxicity on human cancer cells. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.07.031