[Mo(N[i-Pr](3,5-C6H3Me2)3(15)N] | 394247-02-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Mo(N[i-Pr](3,5-C6H3Me2)3(15)N]
• CAS: 394247-02-0
• 化学式: C₃₃H₄₈MoN₄
• 分子量: 597.704
• InChiKey: BVONANPDWXFHKR-RCUQKECRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氮 、 [Na(tetrahydrofuran)x][(Mo(N[i-Pr](3,5-C6H3Me2)3)2(15)N] 以 氘代四氢呋喃 为溶剂， 生成 [Mo(N[i-Pr](3,5-C6H3Me2)3(15)N] 、 [Na(THF)][(Mo(N[i-Pr](3,5-C6H3Me2)3)N2]
  参考文献：
  名称：

  Terminal Phosphide and Dinitrogen Molybdenum Compounds Obtained from Pnictide-Bridged Precursors

  摘要：

  The syntheses of molybdenum terminal phosphide and dinitrogen complexes supported by N-isopropylanilide ligands are not as straightforward as those previously reported for the analogous N-tert-butylanilide complexes, To arrive at these synthetic targets, facile, high-yielding syntheses of bridging pnictide precursors have been developed, and their reduction chemistry has been explored. Cleavage of the reduced mu -E-1 compounds was undertaken using CO and N-2, providing access to the target compounds.

  DOI：

  10.1021/ic015592g