Mono-O-acetyl-2'.3'-epoxy-2'-anhydro-roridinsaeure-dimethylester | 14682-32-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Mono-O-acetyl-2'.3'-epoxy-2'-anhydro-roridinsaeure-dimethylester
• CAS: 14682-32-7
• 化学式: C₁₈H₂₆O₈
• 分子量: 370.4
• InChiKey: GWMVPCBBIMSHSA-FFELTBSMSA-N

物化性质

• 沸点：
  457.1±45.0 °C(predicted)
• 密度：
  1.154±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

反应信息

• 作为反应物：
  描述：

  Mono-O-acetyl-2'.3'-epoxy-2'-anhydro-roridinsaeure-dimethylester 、 乙酸酐 生成 Acetic acid (3E,5Z)-7-acetoxy-2-(5-acetoxy-3-hydroxy-3-methyl-pentyloxy)-1-methyl-hepta-3,5-dienyl ester
  参考文献：
  名称：

  [罗里丁D. Verrucarins和罗里丁的组成，第12页]。

  摘要：

  AbstractThe antibiotic roridin D (C29H38O9), a companion of roridin A, yields on base catalysed hydrolysis verrucarol (3) and the hitherto unknown 2, 3‐epoxy‐2‐anhydrororidinic acid (4) (C14H18O7). Roridin D is a macrocyclic diester to which structure 1 is assigned. In roridin D an epoxy group replaces the hydroxyl group of roridin A.

  DOI：

  10.1002/hlca.19660490818