2,7-diundecyn-1-yl[1]benzothieno[3,2-b][1]benzothiophene | 1003601-95-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻吩类
• 英文名称: 2,7-diundecyn-1-yl[1]benzothieno[3,2-b][1]benzothiophene
• CAS: 1003601-95-3
• 化学式: C₃₆H₄₄S₂
• 分子量: 540.877
• InChiKey: SEBXMHTVOPXHNO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.25
• 重原子数：
  38.0
• 可旋转键数：
  14.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  2,7-diundecyn-1-yl[1]benzothieno[3,2-b][1]benzothiophene 在 palladium on activated charcoal 氢气 作用下， 以 甲苯 为溶剂， 以89%的产率得到2,7-diundecyl[1]benzothieno[3,2-b][1]benzothiophene
  参考文献：
  名称：

  Highly Soluble [1]Benzothieno[3,2-b]benzothiophene (BTBT) Derivatives for High-Performance, Solution-Processed Organic Field-Effect Transistors

  摘要：

  2,7-Dialkyl[1]benzothieno[3,2-b]benzothiophenes were tested as solution-processible molecular semiconductors. Thin films of the organic semiconductors deposited on Si/SiO2 substrates by spin coating have well-ordered structures as confirmed by XRD analysis. Evaluations of the devices under ambient conditions showed typical p-channel FET responses with the field-effect mobility higher than 1.0 cm(2) V-1 S-1 and /(n)//(off) of -10(7).

  DOI：

  10.1021/ja074841i
• 作为产物：
  描述：

  2,7-diiodo[1]benzothieno[3,2-b][1]benzothiophene 、 1-十一炔 在 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 二异丙胺 作用下， 以 苯 为溶剂， 反应 8.0h， 以84%的产率得到2,7-diundecyn-1-yl[1]benzothieno[3,2-b][1]benzothiophene
  参考文献：
  名称：

  Highly Soluble [1]Benzothieno[3,2-b]benzothiophene (BTBT) Derivatives for High-Performance, Solution-Processed Organic Field-Effect Transistors

  摘要：

  2,7-Dialkyl[1]benzothieno[3,2-b]benzothiophenes were tested as solution-processible molecular semiconductors. Thin films of the organic semiconductors deposited on Si/SiO2 substrates by spin coating have well-ordered structures as confirmed by XRD analysis. Evaluations of the devices under ambient conditions showed typical p-channel FET responses with the field-effect mobility higher than 1.0 cm(2) V-1 S-1 and /(n)//(off) of -10(7).

  DOI：

  10.1021/ja074841i