[Ph4P][Fe2((2,2',2''-tris(isobutyrylamido)triphenylamine)(-3H))2K] | 1311412-14-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Ph4P][Fe2((2,2',2''-tris(isobutyrylamido)triphenylamine)(-3H))2K]
• 英文别名: [Ph4P][KFe2(μ-(N(C6H4NC(O)Pr-i)3)-κN:κO)2]
• CAS: 1311412-14-2
• 化学式: C₂₄H₂₀P*C₆₀H₆₆Fe₂KN₈O₆
• 分子量: 1485.42
• InChiKey: VJUKYQNOWMPLEM-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ph4P][Fe2((2,2',2''-tris(isobutyrylamido)triphenylamine)(-3H))2K] 、 氧气 以 N,N-二甲基甲酰胺 为溶剂， 生成 [Ph4P][Fe(N(C6H4NC(O)Pr-i)2(C6H4NC(O)CMe2O))]
  参考文献：
  名称：

  Oxygen Activation and Intramolecular C–H Bond Activation by an Amidate-Bridged Diiron(II) Complex

  摘要：

  A diiron(II) complex containing two mu-1,3(kappa N:kappa O)-amidate linkages has been synthesized using the 2,2',2 ''-tris(isobutyrylamido)triphenylamine (H3LiPr) ligand. The resulting diiron complex, 1, reacts with dioxygen (or iodosylbenzene) to effect intramolecular C-H bond activation at the methine position of the ligand isopropyl group. The ligand-activated product, 2, has been isolated and characterized by a variety of methods including X-ray crystallography. Electrospray ionization mass spectroscopy of 2 prepared from (18)(2) was used to confirm that the oxygen atom incorporated into the ligand framework is derived from molecular oxygen.

  DOI：

  10.1021/ic2007183
• 作为产物：
  描述：

  2,2',2''-tris(isobutylamido)triphenylamine 、 四苯基溴化膦 、 potassium hydride 、 iron(II) acetate 以 N,N-二甲基甲酰胺 为溶剂， 以78%的产率得到[Ph4P][Fe2((2,2',2''-tris(isobutyrylamido)triphenylamine)(-3H))2K]
  参考文献：
  名称：

  Oxygen Activation and Intramolecular C–H Bond Activation by an Amidate-Bridged Diiron(II) Complex

  摘要：

  A diiron(II) complex containing two mu-1,3(kappa N:kappa O)-amidate linkages has been synthesized using the 2,2',2 ''-tris(isobutyrylamido)triphenylamine (H3LiPr) ligand. The resulting diiron complex, 1, reacts with dioxygen (or iodosylbenzene) to effect intramolecular C-H bond activation at the methine position of the ligand isopropyl group. The ligand-activated product, 2, has been isolated and characterized by a variety of methods including X-ray crystallography. Electrospray ionization mass spectroscopy of 2 prepared from (18)(2) was used to confirm that the oxygen atom incorporated into the ligand framework is derived from molecular oxygen.

  DOI：

  10.1021/ic2007183