octadecyl glycolate | 162964-88-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: octadecyl glycolate
• 英文别名: Octadecyl 2-hydroxyacetate
• CAS: 162964-88-7
• 化学式: C₂₀H₄₀O₃
• 分子量: 328.536
• InChiKey: KLGJYXIMXNNNNN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.2
• 重原子数：
  23
• 可旋转键数：
  19
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.95
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  octadecyl glycolate 240.0 ℃ 、500.01 Pa 条件下， 以71.2 %的产率得到1,4-二氧杂环-2,5-己二酮
  参考文献：
  名称：

  A METHOD FOR SYNTHESIZING GLYCOLIDE

  摘要：

  This invention provides a method for synthesizing glycolide using methyl glycolate as a raw material, comprising two steps as illustrated in the following reaction formulas: wherein, the ROH represents a straight/branched chain alcohol, acid or ester containing 18-30 carbons and at least one hydroxyl group. The method for glycolide synthesis disclosed in the present invention manages to maintain a low viscosity within the reaction system by introducing a high-boiling alcohol into the reaction system to form a larger alkoxy glycolate exhibiting a significantly lower molecular weight compared to the typical glycolic acid oligomers utilized in the conventional process. Thus the challenges of coking and inefficient heat transfer encountered in traditional glycolide synthesis routes are effectively addressed.

  公开号：

  US20240287017A1
• 作为产物：
  描述：

  羟乙酸甲酯 、 1,4-二氧杂环-2,5-己二酮 生成 octadecyl glycolate
  参考文献：
  名称：

  A METHOD FOR SYNTHESIZING GLYCOLIDE

  摘要：

  This invention provides a method for synthesizing glycolide using methyl glycolate as a raw material, comprising two steps as illustrated in the following reaction formulas: wherein, the ROH represents a straight/branched chain alcohol, acid or ester containing 18-30 carbons and at least one hydroxyl group. The method for glycolide synthesis disclosed in the present invention manages to maintain a low viscosity within the reaction system by introducing a high-boiling alcohol into the reaction system to form a larger alkoxy glycolate exhibiting a significantly lower molecular weight compared to the typical glycolic acid oligomers utilized in the conventional process. Thus the challenges of coking and inefficient heat transfer encountered in traditional glycolide synthesis routes are effectively addressed.

  公开号：

  US20240287017A1

文献信息

• Lubricating composition containing an antiwear agent
  申请人：The Lubrizol Corporation

  公开号：EP2891700A1

  公开（公告）日：2015-07-08

  The invention provides a lubricating composition containing an oil of lubricating viscosity and a compound obtained/obtainable by a process comprising reacting a glycolic acid, a 2-halo-acetic acid, or a lactic acid, or an alkali or alkaline metal salts thereof, (typically glycolic acid or a 2-halo-acetic acid) with at least one member selected from the group consisting of an amine, an alcohol, and an aminoalcohol. The invention further relates to the use of the lubricating composition in an internal combustion engine.

  本发明提供了一种润滑组合物，该组合物含有一种润滑粘度油和一种通过以下工艺获得的化合物：将乙醇酸、2-卤代乙酸或乳酸或其碱金属盐（通常为乙醇酸或 2-卤代乙酸）与至少一种选自胺、醇和氨基醇的成员进行反应。本发明还涉及润滑组合物在内燃机中的用途。
• Lubricating composition containing a corrosion inhibitor
  申请人：The Lubrizol Corporation

  公开号：EP2891701A1

  公开（公告）日：2015-07-08

  The invention provides a lubricating composition containing an oil of lubricating viscosity and a compound obtained/obtainable by a process comprising reacting a glycolic acid, a 2-halo-acetic acid, or a lactic acid, or an alkali or alkaline metal salts thereof, (typically glycolic acid or a 2-halo-acetic acid) with at least one member selected from the group consisting of an amine, an alcohol, and an aminoalcohol. The invention further relates to the use of the lubricating composition in an internal combustion engine.

  本发明提供了一种润滑组合物，该组合物含有一种润滑粘度油和一种通过以下工艺获得的化合物：将乙醇酸、2-卤代乙酸或乳酸或其碱金属盐（通常为乙醇酸或 2-卤代乙酸）与至少一种选自胺、醇和氨基醇的成员进行反应。本发明还涉及润滑组合物在内燃机中的用途。
• [EN] METHOD FOR SYNTHESIZING GLYCOLIDE<br/>[FR] PROCÉDÉ DE SYNTHÈSE DE GLYCOLIDE<br/>[ZH] 一种合成乙交酯的方法
  申请人：[en]EAST CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY;[zh]华东理工大学

  公开号：WO2022262712A1

  公开（公告）日：2022-12-22

  本发明公开了一种合成乙交酯的方法，以乙醇酸甲酯为原料，通过以下两步反应获得： (一) (二) 其中：所述ROH为含有1个或多个羟基的18～30碳直链或支链醇、酸或酯。本发明的乙交酯合成工艺通过引入高沸点醇参与反应，生成乙醇酸高级酯中间产物，其分子量远远低于传统工艺的中间产物乙醇酸低聚物的分子量，从而控制了反应体系的粘度处于低水平，提高了体系的传热效率，有效地避免了传统低聚路线易结焦碳化的问题。
• EP0751760A4
  申请人：——

  公开号：EP0751760A4

  公开（公告）日：1996-11-07
• METHOD FOR THE TREATMENT AND/OR PREVENTION OF RADIATION BURN
  申请人：PERRICONE, Nicholas V., Dr.

  公开号：EP0751760A1

  公开（公告）日：1997-01-08