24-Oxaundecacyclo[23.20.0.02,23.03,16.04,13.05,10.017,22.026,31.032,45.035,44.038,43]pentatetraconta-1(25),2(23),3(16),4(13),5,7,9,11,14,17,19,21,26,28,30,32(45),33,35(44),36,38,40,42-docosaene | 1330778-85-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 24-Oxaundecacyclo[23.20.0.02,23.03,16.04,13.05,10.017,22.026,31.032,45.035,44.038,43]pentatetraconta-1(25),2(23),3(16),4(13),5,7,9,11,14,17,19,21,26,28,30,32(45),33,35(44),36,38,40,42-docosaene
• CAS: 1330778-85-2
• 化学式: C₄₄H₂₄O
• 分子量: 568.674
• InChiKey: UWBNJSVAEJXNFA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.7
• 重原子数：
  45
• 可旋转键数：
  0
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  13.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  在 tetraphosphorus decasulfide 作用下， 以 甲苯 为溶剂， 以59%的产率得到24-Oxaundecacyclo[23.20.0.02,23.03,16.04,13.05,10.017,22.026,31.032,45.035,44.038,43]pentatetraconta-1(25),2(23),3(16),4(13),5,7,9,11,14,17,19,21,26,28,30,32(45),33,35(44),36,38,40,42-docosaene
  参考文献：
  名称：

  Novel synthesis of oxa[9]helicenes by Lawesson’s reagent-mediated cyclization of helical quinone derivatives

  摘要：

  New oxa[9]helicenes which possess one furan ring have been readily prepared by reactive helical quinone with Lawesson's reagent or phosphorus pentasulfide in good yields. The versatility of this protocol has been demonstrated with various substituted helical quinones. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.06.033