[Eu(2-thenoyltrifluoroacetonate)3(N-ethyl-10H-dipyrido-[f,h]-indolo-[3,2-b]-quinoxaline)] | 1370615-72-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: [Eu(2-thenoyltrifluoroacetonate)3(N-ethyl-10H-dipyrido-[f,h]-indolo-[3,2-b]-quinoxaline)]
• CAS: 1370615-72-7
• 化学式: C₄₆H₂₇EuF₉N₅O₆S₃
• 分子量: 1164.89
• InChiKey: SXKQGHXJBYOIIA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-噻吩甲酰三氟丙酮 、 氢化铕 、 N-ethyl-10H-dipyrido-[f,h]-indolo-[3,2-b]-quinoxaline 在 NaOH 作用下， 以 乙醇 为溶剂， 生成 [Eu(2-thenoyltrifluoroacetonate)3(N-ethyl-10H-dipyrido-[f,h]-indolo-[3,2-b]-quinoxaline)]
  参考文献：
  名称：

  Nanofibers doped with a novel red-emitting Europium complex: Synthesis, characterization, photophysical property and sensing activity toward molecular oxygen

  摘要：

  In this paper, we synthesize a novel diamine ligand of DIQ-Et and its corresponding Eu(III) complex of Eu(TTA)(3)DIQ-Et, where DIQ-Et =N-ethyl-10H-dipyrido-[f,h]-indolo-[3,2-b]-quinoxaline, and TTA = 2-thenoyltrifluoroacetonate. The UV-vis absorption, photoluminescence, low temperature phosphorescence, energy transfer mechanism, and excited state lifetime of Eu(TTA)(3)DIQ-Et are investigated in detail. Data suggest that the emission of Eu(TTA)(3)DIQ-Et is quenchable by molecular oxygen due to the back-energy transfer process. By doping Eu(TTA)(3)DIQ-Et into a polymer matrix of poly(vinylpyrrolidone) (PVP), oxygen sensing performance of the resulted nanofibers is investigated. Finally, the 0.7 wt% doped sample exhibits a linear response toward molecular oxygen, with a sensitivity of 2.4 and response/recovery time of 12 s/16 s. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2012.01.074