叔丁醇铊 | 22520-89-4

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 中文名称: 叔丁醇铊
• 英文名称: thallium tert-butoxide
• 英文别名: tert.-Butoxy-thallium(I)；TlO(t)Bu；(2-Methylpropan-2-yl)oxythallium
• CAS: 22520-89-4
• 化学式: C₄H₉O*Tl
• 分子量: 277.498
• InChiKey: OTPKEYWDOHQQAD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.89
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (R)-1,2,3,4,5-pentamethyl-6-(2,2,3,3-tetramethylcyclopentyl)benzene 、 叔丁醇铊 以 not given 为溶剂， 生成
  参考文献：
  名称：

  A new route to fluorocarbon-stabilized organoamidoplatinum(II) compounds—synthesis of a new isomer of [Me2)X(L)] (R = p-HC6F4 OR C6F5; X = Cl or I; L = unidentate ligand) complexes

  摘要：

  DOI：

  10.1016/s0277-5387(00)86296-8

文献信息

• A Flexible, Extremely Sterically Demanding Triazenide Ligand: Synthesis and Coordination Chemistry
  作者：Matthew R. Gyton、Mohan Bhadbhade、Marcus L. Cole

  DOI：10.1002/zaac.201900050

  日期：2019.6.14

  suggests these interactions are fluxional in solution. The variability of these interactions in the solid state as well as the changes in calculated steric demand of the ligand between metals point to an adaptive, flexible coordination mode.

  为了进一步研究极度拥挤的主族金属，据报道合成了一种新的低聚芳基三氮烯（Dipp * 2 N 3 H）。通过将Dipp * NH 2重氮化以高产率且可扩展的制备方式来获得Dipp * I和Dipp * N 3来进行访问。由于难以通过芳基锂物种获得纯的三氮烯，这些化合物通过芳基镁用作Dipp * 2 N 3 H的前体。与钾和铊的三氮烯的去质子化叔丁醇盐可高产率地得到相应的金属三叠氮化物。确定了这些络合物的固态结构，并在每种情况下观察到了三种高触觉的金属芳烃-π相互作用，它们在空间上屏蔽了金属中心。光谱的C 2 v对称性表明这些相互作用在溶液中是流动的。这些相互作用在固态中的可变性以及金属之间配体的计算出的空间需求的变化表明了一种自适应的，灵活的配位模式。
• Erikson, Torsten K. G.; Bryan, Jeffrey C.; Mayer, James M., Organometallics, 1988, vol. 7, # 9, p. 1930 - 1938
  作者：Erikson, Torsten K. G.、Bryan, Jeffrey C.、Mayer, James M.

  DOI：——

  日期：——
• Mononuclear (<i>O</i>,<i>O</i>′ or <i>N</i>,<i>N</i>′) and Heterodinuclear (<i>O</i>,<i>O</i>′ and <i>N</i>,<i>N</i>′) Transition-Metal Complexes of <i>ortho</i>-Quinoid Bis(pyrazol-1-yl)methane Ligands
  作者：Florian Blasberg、Michael Bolte、Hans-Wolfram Lerner、Matthias Wagner

  DOI：10.1021/om3000746

  日期：2012.4.23

  The ortho-hydroquinone-substituted bis(3,5-dimethylpyrazol-1-yl)methane ligand (HO)(2)C6H3-C(H)-(Pz(Me,Me))(2) (7) has been synthesized and fully characterized. Together with its bis(3-tert-butylpyrazol-1-yl)methane congener (HO)(2)C6H3-C(H)(pz(tBu))(2) (6), 7 was employed in oxidation and complexation studies. 6 has been oxidized with 2,3-dichloro-5,6-dicyano-para-benzoquinone to the corresponding ortho-benzoquinone form 9 on a preparative scale. Pure samples of 9 are stable for several hours in solution and for approximately one day in the solid state. Attempts at a N,N' coordination of [PdCl2] to 6 led to decomposition of the -C(H)(pz(tBu))(2) moiety, whereas an introduction of [PdCl2] exclusively at the N,N' site was possible in high yield for ligand 7. A selectively O,O'-chelated [(p-cym)Ru](2+) complex was accessible for ligand 6, but not for 7. In contrast, [(ppy)(2)Ir](+) and [(Cp*)Ir](2+) gave O,O' complexes with both donors 6 and 7 (Hppy = 2-phenylpyridine; HCp* = pentamethylcyclopentadiene). The heterodinuclear complex [(Cp*)Ir(O)(2)C6H3-C(H)(pz(Me,Me))(2)PdCl2] (16) was obtained from 14 and [(MeCN)(2)PdCl2].