Cu(Me2NH)2(1,1-diamino-2,2-dinitroethene(1-))2 | 1260020-28-7

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: Cu(Me2NH)2(1,1-diamino-2,2-dinitroethene(1-))2
• CAS: 1260020-28-7
• 化学式: C₈H₂₀CuN₁₀O₈
• 分子量: 447.855
• InChiKey: ZXQSVPJGKSDZOB-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  二甲胺 、 guanidinium(1+) 1,1-diamino-2,2-dinitroethene(1-) 、 copper(II) nitrate trihydrate 以 水 为溶剂， 以67%的产率得到Cu(Me2NH)2(1,1-diamino-2,2-dinitroethene(1-))2
  参考文献：
  名称：

  FOX-7 (1,1-Diamino-2,2-dinitroethene): Trapped by Copper and Amines

  摘要：

  Syntheses of the first Cu(NH3)(2)(FOX)(2) and various Cu(amine)(2)(FOX)(2) (methyl, propyl, and dimethyl amine) complexes were achieved by using metathetical reactions which add a new chapter to the metal chemistry of FOX-7 (1,1-diamino-2,2-dintroethene). The crystal structures of Cu(NH3)(2)(FOX)(2) and Cu(C3H7NH2)(2)(FOX)(2) which show square planar geometry at copper aid in the understanding of the bonding modes in FOX-7 copper complexes which is supported by natural bond orbital (NBO) calculations. Water-free K-FOX was also structured.

  DOI：

  10.1021/ic102136r