ethylenediamine[(2-phenyl)(3-phenyl-2-ido)quinoxalin]palladium(II) perchlorate | 303045-40-1

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: ethylenediamine[(2-phenyl)(3-phenyl-2-ido)quinoxalin]palladium(II) perchlorate
• CAS: 303045-40-1
• 化学式: C₂₂H₂₁N₄Pd*ClO₄
• 分子量: 547.306
• InChiKey: HHYIVKVNORWKMN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [((2-phenyl)(3-phenyl-2-ido)quinoxalin)(μ-Cl)]2 、 乙二胺 以 not given 为溶剂， 以80%的产率得到ethylenediamine[(2-phenyl)(3-phenyl-2-ido)quinoxalin]palladium(II) perchlorate
  参考文献：
  名称：

  Spectroscopic and electrochemical properties of cyclopalladated complexes of 2,3-diphenylquinoxaline and 2,2′,3,3′-tetraphenyl-6,6′-biquinoline

  摘要：

  Comparative study of cyclopalladated ethylenediamine complexes of 2,3-diphenylquinoxaline (Hdphqx) [Pd(dphqx)En]ClO4 and 2,2 ',3,3 '-tetraphenylbiquinoline (H(2)tphbq) [(PdEn)(2)(mu-tphbq)](ClO4)(2), and the free heterocyclic ligands was performed by means of H-1 NMR spectroscopy, electronic absorption and emission spectroscopy, and cyclic voltammetry. It was shown that cyclopalladation gives rise to a long-wave absorption band in the visible spectrum, a batochromic shift of the vibrationally structured phosphorescence band, and an anodic shift of the ligand-centered reduction potential of the complexes com-pared to free ligands.

  DOI：

  10.1134/s1070363208040257

文献信息

• Kulikova; Balashev; Kvam, Russian Journal of General Chemistry, 2000, vol. 70, # 2, p. 163 - 170
  作者：Kulikova、Balashev、Kvam、Songstad

  DOI：——

  日期：——