3-{(1H,1H,10H,10H-perfluoro-1-tert-butoxycarbonyloxy-10-carbonyloxydecane)}propionic acid | 224569-76-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 3-{(1H,1H,10H,10H-perfluoro-1-tert-butoxycarbonyloxy-10-carbonyloxydecane)}propionic acid
• 英文别名: 4-[2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-Hexadecafluoro-10-[(2-methylpropan-2-yl)oxycarbonyloxy]decoxy]-4-oxobutanoic acid
• CAS: 224569-76-0
• 化学式: C₁₉H₁₈F₁₆O₇
• 分子量: 662.322
• InChiKey: IZIWWEHLSWDAFV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  42
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.84
• 拓扑面积：
  99.1
• 氢给体数：
  1
• 氢受体数：
  23

反应信息

• 作为产物：
  描述：

  二碳酸二叔丁酯 在 4-二甲氨基吡啶 、 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 4.0h， 生成 3-{(1H,1H,10H,10H-perfluoro-1-tert-butoxycarbonyloxy-10-carbonyloxydecane)}propionic acid
  参考文献：
  名称：

  Switching surface polarity: synthesis and characterization of a fluorinated block copolymer with surface‐active tert ‐butoxycarbonyl groups

  摘要：

  The surface behavior of a series of block copolymers constructed from poly(styrene-b-semifluorinated side-chain modified isoprene) copolymer was evaluated. The semifluorinated side groups were attached in a postpolymerization step. The presence of tert-butoxy carbonyl end groups permitted conversion of the polymer surface from a non-polar hydrocarbon to a polar hydroxylated structure. The microstructure of these block copolymers was investigated using both electron microscopy and small-angle x-ray diffraction. The surface properties of the as-prepared polymer films were dominated by the fluorinated block and were found to be independent of the underlying block copolymer microstructure. After removal of the tert-butoxy carbonyl end groups, a disordered, polar surface was produced. The surface properties of these films were studied using contact angle measurements and other surface analysis techniques. Copyright (C) 2000 John Wiley & Sons, Ltd.

  DOI：

  10.1002/1099-1395(200012)13:12<787::aid-poc326>3.0.co;2-#