[Pt(2,2',6',2''-terpyridine)CCPhC12H25-p](OTf) | 1256701-50-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [Pt(2,2',6',2''-terpyridine)CCPhC12H25-p](OTf)
• 英文别名: [Pt(trpy)CCPhC12H25-p](OTf)
• CAS: 1256701-50-4
• 化学式: CF₃O₃S*C₃₅H₄₀N₃Pt
• 分子量: 846.873
• InChiKey: JMDSMWGQIGYXCR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  chloro(2,2':6',2''-terpyridine)platinum(II) trifluoromethanesulfonate 、 1-十二烷基-4-乙炔基苯 在 CuI 、 (C₂H₅)3N 作用下， 以 二氯甲烷 为溶剂， 以70%的产率得到[Pt(2,2',6',2''-terpyridine)CCPhC12H25-p](OTf)
  参考文献：
  名称：

  Controlled emission of platinum(II) terpyridyl complexes with poly-l-glutamic acid

  摘要：

  Poly-L-glutamic acid, P(Glu), bearing multiple negatively charged side chains served as a polymeric spatially aligned scaffold for the aggregation of positively charged platinum(II) complexes [Pt(trpy)C equivalent to CR](OTf) (trpy = 2,2',6',2 ''-terpyridine; R = Ph (PtH), PhC12H25-p (PtC12)) through electrostatic interaction, resulting in tunable emission properties. PtC12 was found to exhibit gradual increase in the emission intensity based on the triplet metal-metal-to-ligand charge transfer ((MMLCT)-M-3) in a tris/HCl buffer (pH 7.6)/MeOH (v/v = 1/14) solution with concomitant decrease in the emission intensity based on the triplet metal-to-ligand charge transfer ((MLCT)-M-3)/the triplet ligand-to-ligand charge transfer ((LLCT)-L-3) as the amount of P(Glu) was increased. Such synergistic effect was not observed in the case of PtH, wherein the emission intensity based on (MLCT)-M-3/(LLCT)-L-3 was increased by the increase in the amount of P(Glu), indicating that alkyl long chain of PtC12 is considered to play an important role in the aggregation of the platinum(II) terpyridyl moieties to show Pt(II)-Pt(II) and pi-pi interactions. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.07.024