| 1246557-97-0

• 分子结构分类: 有机化合物 - 有机杂环化合物
• CAS: 1246557-97-0
• 化学式: C₂₉H₂₀N₂O₂Zn
• 分子量: 493.88
• InChiKey: VESPQZLOLUTTNC-LZVQHCPISA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,2-C6H4(2-NCMeC10H6OH)(NCHC10H6OH-2) 、 zinc diacetate 以 乙醇 、 二氯甲烷 为溶剂， 以50%的产率得到
  参考文献：
  名称：

  Synthesis and Crystal Structure of Non-symmetric Tetradentate Complexes of Ni(II), Cu(II), Co(II), and Zn(II)

  摘要：

  The non-symmetrical tetradentate Schiff-base H(2)L have been obtained using the half-unit N-(1-hydroxy-2-acetonaphthone)-1-amino-2-phenyleneimine (HL(1)) with 2-hydroxyl-1-naphthaldehyde. ML complexes(M= Ni(1), Cu(2), Co(3) and Zn(4)) were prepared and characterized by atomic absorption, IR, UV, (1)H NMR spectroscopy, and a single crystal X-ray structure. Crystal data for (1) are triclinic space group P-1, a = 7.9784 (3) angstrom, b = 10.2417 (4) angstrom, c = 13.4090 (5) angstrom, alpha = 103.8480 (10)degrees, beta = 97.0540 (10)degrees, gamma = 92.2400 (10)degrees and z = 2. Crystal data for (2): Triclinic space group P-1, a = 7.9991 (6) angstrom, b = 10.0520 (7) angstrom, c = 13.6974 (10) angstrom, alpha = 103.6500 (10)degrees, beta = 95.9650 (10)degrees, gamma = 90.3160 (10)degrees and z = 2. The Ni and Cu atoms have slightly distorted square-planar coordination geometry.

  DOI：

  10.1080/15533174.2010.492547