1,2-C6H4(2-NCMeC10H6OH)(NCHC10H6OH-2) | 303732-09-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,2-C6H4(2-NCMeC10H6OH)(NCHC10H6OH-2)
• CAS: 303732-09-4
• 化学式: C₂₉H₂₂N₂O₂
• 分子量: 430.506
• InChiKey: YNIYZQCNHBSWRW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  33.0
• 可旋转键数：
  4.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  65.18
• 氢给体数：
  2.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  1,2-C6H4(2-NCMeC10H6OH)(NCHC10H6OH-2) 、 copper diacetate 以 乙醇 为溶剂， 以74%的产率得到1,2-C6H4(2-NCMeC10H6O)(NCHC10H6O-2)Cu
  参考文献：
  名称：

  Synthesis and Crystal Structure of Non-symmetric Tetradentate Complexes of Ni(II), Cu(II), Co(II), and Zn(II)

  摘要：

  The non-symmetrical tetradentate Schiff-base H(2)L have been obtained using the half-unit N-(1-hydroxy-2-acetonaphthone)-1-amino-2-phenyleneimine (HL(1)) with 2-hydroxyl-1-naphthaldehyde. ML complexes(M= Ni(1), Cu(2), Co(3) and Zn(4)) were prepared and characterized by atomic absorption, IR, UV, (1)H NMR spectroscopy, and a single crystal X-ray structure. Crystal data for (1) are triclinic space group P-1, a = 7.9784 (3) angstrom, b = 10.2417 (4) angstrom, c = 13.4090 (5) angstrom, alpha = 103.8480 (10)degrees, beta = 97.0540 (10)degrees, gamma = 92.2400 (10)degrees and z = 2. Crystal data for (2): Triclinic space group P-1, a = 7.9991 (6) angstrom, b = 10.0520 (7) angstrom, c = 13.6974 (10) angstrom, alpha = 103.6500 (10)degrees, beta = 95.9650 (10)degrees, gamma = 90.3160 (10)degrees and z = 2. The Ni and Cu atoms have slightly distorted square-planar coordination geometry.

  DOI：

  10.1080/15533174.2010.492547
• 作为产物：
  描述：

  N-(1-hydroxy-2-acetonaphthone)-1-amino-2-phenyleneimine 、 2-羟基-1-萘甲醛 在 哌啶 作用下， 以 甲醇 为溶剂， 反应 0.5h， 以85%的产率得到1,2-C6H4(2-NCMeC10H6OH)(NCHC10H6OH-2)
  参考文献：
  名称：

  Synthesis and Crystal Structure of Non-symmetric Tetradentate Complexes of Ni(II), Cu(II), Co(II), and Zn(II)

  摘要：

  The non-symmetrical tetradentate Schiff-base H(2)L have been obtained using the half-unit N-(1-hydroxy-2-acetonaphthone)-1-amino-2-phenyleneimine (HL(1)) with 2-hydroxyl-1-naphthaldehyde. ML complexes(M= Ni(1), Cu(2), Co(3) and Zn(4)) were prepared and characterized by atomic absorption, IR, UV, (1)H NMR spectroscopy, and a single crystal X-ray structure. Crystal data for (1) are triclinic space group P-1, a = 7.9784 (3) angstrom, b = 10.2417 (4) angstrom, c = 13.4090 (5) angstrom, alpha = 103.8480 (10)degrees, beta = 97.0540 (10)degrees, gamma = 92.2400 (10)degrees and z = 2. Crystal data for (2): Triclinic space group P-1, a = 7.9991 (6) angstrom, b = 10.0520 (7) angstrom, c = 13.6974 (10) angstrom, alpha = 103.6500 (10)degrees, beta = 95.9650 (10)degrees, gamma = 90.3160 (10)degrees and z = 2. The Ni and Cu atoms have slightly distorted square-planar coordination geometry.

  DOI：

  10.1080/15533174.2010.492547

文献信息

• Metal Complexes of Non-Symmetric Tetradentate Schiff Bases Derived from N-(1-hydroxy-2-acetonaphthone)-1-amino-2-phenyleneimine
  作者：Davar M. Boghaei、Maryam Lashanizadegan

  DOI：10.1080/00945710009351841

  日期：2000.8.1