1-(4-methoxyphenyl)-1-(5-phenyl-4-pentynyl)silacyclobutane | 1335225-12-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-(4-methoxyphenyl)-1-(5-phenyl-4-pentynyl)silacyclobutane
• CAS: 1335225-12-1
• 化学式: C₂₁H₂₄OSi
• 分子量: 320.506
• InChiKey: BRBIVUVTKSCZSJ-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  1-(4-methoxyphenyl)-1-(5-phenyl-4-pentynyl)silacyclobutane 在 allyl(cyclopentadiene)palladium(II) 、 10,16-dimethyl-N,N-bis[(1S)-1-phenylethyl]-12,14-dioxa-13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3(8),9,16,18(23)-hexaen-13-amine 作用下， 以 甲苯 为溶剂， 生成 、 (4R)-4-(4-methoxyphenyl)-8-phenyl-1,2,3,5,6,7-hexahydrosilolo[1,2-a]siline 、
  参考文献：
  名称：

  Palladium-Catalyzed Enantioselective Desymmetrization of Silacyclobutanes: Construction of Silacycles Possessing a Tetraorganosilicon Stereocenter

  摘要：

  A palladium-catalyzed desymmetrization of alkyne-tethered silacyclobutanes to give silacycles possessing a tetraorganosilicon stereocenter has been developed, and high chemo- and enantioselectivities have been achieved by the use of a newly synthesized chiral phosphoramidite ligand.

  DOI：

  10.1021/ja208621x