copper(I) 1-carbamothioyl-2-(4-methoxybenzylidene)hydrazin-1-ide | 76077-75-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: copper(I) 1-carbamothioyl-2-(4-methoxybenzylidene)hydrazin-1-ide
• CAS: 76077-75-3
• 化学式: C₉H₁₀N₃OS*Cu
• 分子量: 271.81
• InChiKey: QVTCZGQRMIGPPM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.64
• 重原子数：
  15.0
• 可旋转键数：
  3.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  61.71
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  4-methoxybenzylidene thiosemicarbazone 、 copper(II) acetate monohydrate 以 乙醇 为溶剂， 生成 copper(I) 1-carbamothioyl-2-(4-methoxybenzylidene)hydrazin-1-ide
  参考文献：
  名称：

  Coordination compounds of hydrazine derivatices with transition metals—XIX

  摘要：

  DOI：

  10.1016/0022-1902(80)80426-x

文献信息

• Synthesis, Magnetic Measurements and Spectroscopic Studies of Copper(I) and Copper(II) Complexes of Thiosemicarbazones Derived from Aromatic Aldehydes and Ketones
  作者：Naraylan T. Akinchan、Richa Akinchan、Piotr M. Drozdzewski、Yong Hong Yang、Tracey L. Klein、Douglas X. West

  DOI：10.1080/00945719608004404

  日期：1996.11

  Copper(I) and copper(II) complexes of the thiosemicarbazone derivatives of p-anisaldehyde (ATSZH), p-tolualdehyde (TTSZH), vanillin (VTSZH) and fluorenone (FTSZH) have been prepared and characterized by elemental analysis; IR, Raman and electronic spectral studies; and magnetic measurements. Changes in selected vibrational absorptions of the ligands upon coordination are discussed. Based on magnetic and spectroscopic data, the structures for the complexes are proposed as follows: polymeric for [Cu(TTSZ)(n), [Cu(ATSZ)(n) and [Cu(VTSZ)(n) . nH(2)O and ligand bridged binuclear for [Cu(VTSZ)Cl](2) . H2O, [Cu(VTSZ)(CH3COO)](2), [Cu(FTSZ)(2)](2) . 2H(2)O, and [Cu(FTSZ)Cl](2) . 2H(2)O.