(4-bromo-phenyl)-dimethyl-phosphine | 20690-69-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (4-bromo-phenyl)-dimethyl-phosphine
• 英文别名: (4-Brom-phenyl)-dimethyl-phosphin；(p-Brom-phenyl)-dimethyl-phosphin；(4-Bromophenyl)-dimethylphosphane
• CAS: 20690-69-1
• 化学式: C₈H₁₀BrP
• 分子量: 217.045
• InChiKey: OXIWYEJOTIEGEP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  二硫化碳 、 (4-bromo-phenyl)-dimethyl-phosphine 在 苯 作用下， 生成 (4-bromo-phenyl)-dithiocarboxy-dimethyl-phosphonium betaine
  参考文献：
  名称：

  418.叔膦的一些加成化合物的组成

  摘要：

  DOI：

  10.1039/jr9350001786
• 作为产物：
  描述：

  4-Bromphenylphosphindichlorid 、 alkaline earth salt of/the/ methylsulfuric acid 生成 (4-bromo-phenyl)-dimethyl-phosphine
  参考文献：
  名称：

  418.叔膦的一些加成化合物的组成

  摘要：

  DOI：

  10.1039/jr9350001786

文献信息

• PHOSPHOROUS DERIVATIVES AS KINASE INHIBITORS
  申请人：ARIAD PHARMACEUTICALS, INC.

  公开号：US20150225436A1

  公开（公告）日：2015-08-13

  The invention features compounds of the general formula: in which the variable groups are as defined herein, and to their preparation and use.

  该发明涉及一般式化合物：其中变量基团如本文所定义，以及它们的制备和使用。
• PHOSPHORUS DERIVATIVES AS KINASE INHIBITORS
  申请人：Wang Yihan

  公开号：US20120202776A1

  公开（公告）日：2012-08-09

  The invention features compounds of the general formula (I) in which the variable groups are as defined herein, and to their preparation and use.

  该发明涉及通式（I）中变量基团如此定义的化合物，以及它们的制备和使用。
• Phosphorus Derivatives as Kinase Inhibitors
  申请人：ARIAD PHARMACEUTICALS, INC.

  公开号：US20130225527A1

  公开（公告）日：2013-08-29

  The invention features compounds of the general formula: in which the variable groups are as defined herein, and to their preparation and use.

  本发明涉及一般式化合物：其中变量基团的定义如本文所述，以及其制备和使用。
• Organic Semiconductive Layer Comprising Phosphine Oxide Compounds
  申请人：Novaled GmbH

  公开号：US20180337339A1

  公开（公告）日：2018-11-22

  The present invention relates to an. organic semiconductive layer which is an electron transport layer and/or an electron injection layer and/or an n-type charge generation layer, the organic semiconductive layer comprising at least one compound of formula (1) wherein R 1 and R 2 are each independently selected from C 1 to C 16 alkyl; Ar 1 is selected from C 6 to C 14 arylene or C 3 to C 12 heteroarylene; Ar 2 is independently selected from C 14 to C 40 arylene or C 8 to C 40 heteroarylene; R 3 is independently selected from H, C 1 to C 12 alkyl or C 10 to C 20 aryl; wherein each of Ar 1 , Ar 2 and R 3 may each independently be unsubstituted or substituted with at least one C 1 to C 12 alky group; n is 0 or 1; and m is 1 in case of n=0; and m is 1 or 2 in case of n=1, phosphine oxide compounds comprised therein and to organic electroluminescent devices comprising such layers and compounds.
• Organic Electronic Device Comprising an Organic Semiconductor Layer
  申请人：Novaled GmbH

  公开号：US20200161559A1

  公开（公告）日：2020-05-21

  The present invention relates to a compound of formula 1 and an organic electronic device comprising an organic semiconductor layer, wherein at least one organic semiconductor layer comprises a compound of formula (1), wherein L 1 has the formula (2) and L 2 has the formula (3), wherein L 1 and L 2 are bonded at “*” via a single bond independently to the same or different arylene groups or heteroarylenes group of Ar 1 ; and wherein X 1 , X 2 are independently selected from O, S and Se; Ar 1 is selected from substituted or unsubstituted C 20 to C 52 arylene or C 14 to C 64 heteroarylene, wherein the substituent of the substituted C 20 to C 52 arylene or C 14 to C 64 heteroarylene are independently selected from C 1 to C 12 alkyl, C 1 to C 12 alkoxy, CN, halogen, OH, C 6 to C 25 aryl and C 2 to C 21 heteroaryl; R 1 , R 2 are independently selected from substituted or unsubstituted C 1 to C 16 alkyl, wherein the substituent of substituted C 1 to C 16 alkyl is selected from C 6 to C 18 arylene or C 2 to C 12 heteroarylene; R 3 , R 4 are independently selected from substituted or unsubstituted C 1 to C 16 alkyl, substituted or unsubstituted C 6 to C 18 arylene, C 2 to C 20 heteroarylene, wherein the substituent of substituted C 1 to C 16 alkyl, the substituent of the substituted C 6 to C 18 arylene, C 2 to C 20 heteroarylene are independently selected from C 6 to C 18 arylene or C 2 to C 12 heteroarylene; n is selected from 1 to 5, wherein n is an integer number.