4,4'-bis[4''-(4'''-chlorobenzoyl)phenoxy](hexafluoroisopropylidene)dibenzene | 389634-34-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-bis[4''-(4'''-chlorobenzoyl)phenoxy](hexafluoroisopropylidene)dibenzene
• 英文别名: 2,2-bis[4-{4-(4-chloro-benzoyl)phenoxy}phenyl]-1,1,1,3,3,3-hexafluoropropane；2,2-Bis[4-{4-(4-chlorobenzoyl)phenoxy}phenyl]-1,1,1,3,3,3-hexafluoropropane；[4-[4-[2-[4-[4-(4-chlorobenzoyl)phenoxy]phenyl]-1,1,1,3,3,3-hexafluoropropan-2-yl]phenoxy]phenyl]-(4-chlorophenyl)methanone
• CAS: 389634-34-8
• 化学式: C₄₁H₂₄Cl₂F₆O₄
• 分子量: 765.536
• InChiKey: RTXSRZARSVOFPR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.9
• 重原子数：
  53
• 可旋转键数：
  10
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  4,4'-bis[4''-(4'''-chlorobenzoyl)phenoxy](hexafluoroisopropylidene)dibenzene 在 [nickel(II)(pyridine)4(chloride)2] 四丁基碘化铵 、 三苯基膦 、 锌 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 反应 7.0h， 以28%的产率得到16,16-Bis(trifluoromethyl)-11,21-dioxaheptacyclo[25.2.2.22,5.27,10.212,15.217,20.222,25]hentetraconta-1(30),2(41),3,5(40),7,9,12,14,17(35),18,20(34),22(33),23,25(32),27(31),28,36,38-octadecaene-6,26-dione
  参考文献：
  名称：

  极度应变大环芳族醚砜的合成和扩环低聚。

  摘要：

  [反应：请参阅文本]一种极易拉紧的5环大环芳香醚砜[-1,4-C（6）H（4）SO（2）-1,4-C（6）H（4 ）O-1,3-C（6）H（4）O-1,4-C（6）H（4）SO（2）-1,4-C（6）H（4）-]，合成通过镍催化的双氯苯撑封端的前体的分子内偶联，在稀溶液中进行氟化物促进的环膨胀，得到一系列更高的大环低聚物，包括环状二聚体，三聚体和四聚体。后者在92个原子的环中包含20个芳香族残基，是晶体学上表征的最大的合成有机大环之一。还报道了相关大环醚酮的合成，结构和环扩展。

  DOI：

  10.1021/ol010201n
• 作为产物：
  描述：

  六氟双酚 A 、 4-氯-4-氟苯甲酮 在 potassium carbonate 作用下， 以 甲醇 、 N,N-二甲基乙酰胺 、 甲苯 为溶剂， 以65 g (85%)的产率得到4,4'-bis[4''-(4'''-chlorobenzoyl)phenoxy](hexafluoroisopropylidene)dibenzene
  参考文献：
  名称：

  Halogenated aromatic compound, polymer thereof, and proton-conductive membrane comprising same

  摘要：

  公开号：

  EP1245555B1

文献信息

• NOVEL AROMATIC COMPOUND AND POLYARYLENE COPOLYMER HAVING NITROGEN-CONTAINING HETEROCYCLE INCLUDING SULFONIC ACID GROUP IN SIDE CHAIN
  申请人：Kadota Toshiaki

  公开号：US20100152308A1

  公开（公告）日：2010-06-17

  Provided is a solid polymer electrolyte having increased heat resistance and high proton conductivity and a proton conductive membrane composed of the electrolyte. Also provided is a copolymer having a sulfonic acid group. The copolymer includes a repeating unit represented by Formula (1): (in the formula, Y denotes at least one kind of structure selected from the group consisting of —CO—, —SO 2 —, —SO—, —CONH—, —COO—, —(CF 2 ) l — (l is an integer of 1 to 10), and —C(CF 3 ) 2 —; W denotes at least one kind of structure selected from the group consisting of a direct bond, —CO—, —SO 2 —, —SO—, —CONH—, —COO—, —(CF 2 ) l — (l is an integer of 1 to 10), —C(CF 3 ) 2 —, —O—, and —S—; Z denotes a direct bond or at least one kind of structure selected from the group consisting of —(CH 2 ) l —(l is an integer of 1 to 10), —C(CH 3 ) 2 —, —O—, —S—, —CO—, and —SO 2 —; R 30 denotes a nitrogen-containing aromatic ring having a substituent represented by —SO 3 H, —O(CH 2 ) h SO 3 H, or —O(CF 2 ) h SO 3 H (h is an integer of 1 to 12); p is an integer of 0 to 10; q is an integer of 0 to 10; r is an integer of 1 to 5; and k is an integer of 0 to 4).

  提供了一种具有增强耐热性和高质子导电性的固体聚合物电解质，以及由该电解质组成的质子导电膜。还提供了一种具有磺酸基团的共聚物。该共聚物包括由式（1）表示的重复单元：（在公式中，Y表示来自由- CO-、- SO2-、- SO-、- CONH-、- COO-、-（CF2）l-（l为1至10的整数）、和- C（CF3）2-等结构中至少一种的结构；W表示来自由直接键、- CO-、- SO2-、- SO-、- CONH-、- COO-、-（CF2）l-（l为1至10的整数）、- C（CF3）2-、- O-、和- S-等结构中至少一种的结构；Z表示直接键或来自由-（CH2）l-（l为1至10的整数）、- C（CH3）2-、- O-、- S-、- CO-、和- SO2-等结构中至少一种的结构；R30表示含有一个取代基为- SO3H、- O（CH2）hSO3H、或- O（CF2）hSO3H（h为1至12的整数）的氮含有芳香环；p为0至10的整数；q为0至10的整数；r为1至5的整数；k为0至4的整数）。
• METHOD FOR MANUFACTURING CONJUGATED AROMATIC COMPOUND
  申请人：Oda Seiji

  公开号：US20110275859A1

  公开（公告）日：2011-11-10

  A method for manufacturing a conjugated aromatic compound comprising reacting an aromatic compound (A) wherein one or two leaving groups selected from the group consisting of an iodine atom, a bromine atom and a chlorine atom are bonded to an aromatic ring and the aromatic compound (A) does not have (c1) a group represented by the following formula (10): wherein A 1 represents a C1-C20 alkoxy group etc.; (g1) a C1-C20 alkyl group which may be substituted with a fluorine atom etc.; and (h1) a C2-C20 acyl group which may be substituted with a fluorine atom etc., at the neighboring carbon atom to the carbon atom to which the leaving group is bonded, with an aromatic compound (A) having the same structure as that of the above-mentioned aromatic compound (A) or an aromatic compound (B) wherein the aromatic compound (B) is structurally different from the above-mentioned aromatic compound (A), one or two leaving groups selected from the group consisting of an iodine atom, a bromine atom and a chlorine atom are bonded to an aromatic ring and the aromatic compound (B) does not have the above-mentioned (c1), (g1) and (h1) at the neighboring carbon atom to the carbon atom to which the leaving group is bonded, in the presence of (i) a nickel compound, (ii) a metal reducing agent, (iii) at least one ligand (L1) selected from the group consisting of a 2,2′-bipyridine compound having at least one electron-withdrawing group and having no substituent at 3-, 6-, 3′- and 6′-positions, and a 1,10-phenanthroline compound having at least one electron-withdrawing group and having no substituent at 2- and 9-positions, and (iv) at least one ligand (L2) selected from the group consisting of a 2,2′-bipyridine compound having at least one electron-releasing group and having no substituent at 3-, 6-, 3′- and 6′-positions, and a 1,10-phenanthroline compound having at least one electron-releasing group and having no substituent at 2- and 9-positions.

  一种制备共轭芳香化合物的方法，包括将含有一个或两个离去基团的芳香化合物（A）与含有相同结构的上述芳香化合物（A）或结构不同的芳香化合物（B）反应，其中这些离去基团选自碘原子、溴原子和氯原子，与芳香环结合，而芳香化合物（A）没有以下式（10）所代表的基团：其中A1代表C1-C20烷氧基等；（g1）代表C1-C20烷基基团，可能被氟原子等取代；以及（h1）代表C2-C20酰基基团，可能被氟原子等取代，与离去基团结合的碳原子的相邻碳原子处没有上述（c1）、（g1）和（h1），在（i）镍化合物、（ii）金属还原剂、（iii）从2,2′-联吡啶化合物和1,10-邻菲啰啉化合物中选择的至少一种配体（L1），具有至少一个吸电子基团且在3-、6-、3′-和6′-位置没有取代基，以及（iv）从2,2′-联吡啶化合物和1,10-邻菲啰啉化合物中选择的至少一种配体（L2），具有至少一个释电子基团且在3-、6-、3′-和6′-位置没有取代基团的情况下，在上述离去基团结合的碳原子的相邻碳原子处进行反应。
• Polyarylene, Process For Producing The Same, Solid Polyelectrolyte, And Proton-Conductive Film
  申请人：Yamakawa Yoshitaka

  公开号：US20080015389A1

  公开（公告）日：2008-01-17

  A polyarylene having a structural unit shown by the following formula (1) is disclosed. wherein X and Y indicate a divalent organic group or a single bond, Z shows an oxygen atom or a sulfur atom, R represents at least one atom or group selected from the group consisting of a hydrogen atom, a fluorine atom, an alkyl group, and a fluorine-substituted alkyl group, a is an integer of 1 to 20, n is an integer of 1 to 5, and p is an integer of 1 to 10.

  披氏芳烃具有以下公式（1）所示的结构单元，其中X和Y表示二价有机基团或单键，Z表示氧原子或硫原子，R代表至少选择自氢原子、氟原子、烷基团和氟代烷基团组成的一种原子或基团，a为1至20之间的整数，n为1至5之间的整数，p为1至10之间的整数。
• NITROGENATED AROMATIC COMPOUND, PROCESS FOR PRODUCTION OF THE SAME, POLYMER, AND PROTON CONDUCTIVE MEMBRANE
  申请人：Higami Makoto

  公开号：US20090149623A1

  公开（公告）日：2009-06-11

  A nitrogen-containing aromatic compound is represented by Formula (1). A polymer is obtained by polymerizing the compound. wherein X is an atom or a group selected from halogen atoms other than fluorine and —OSO 2 Rb (wherein Rb is an alkyl group, a fluorine-substituted alkyl group or an aryl group); Y is at least one structure selected from the group consisting of —CO—, —SO 2 —, —SO—, —CONH—, —COO—, —(CF 2 ) l — (wherein l is an integer of 1 to 10) and —C(CF 3 ) 2 —; Z is at least one structure selected from the group consisting of a direct bond, —O— and —S—; R 20 is a nitrogen-containing heterocyclic group; q is an integer of 1 to 5; and p is an integer of 0 to 4.

  一个含氮芳香化合物由式（1）表示。通过聚合该化合物得到一种聚合物。其中X是从卤素原子（不包括氟）和—OSO2Rb（其中Rb是烷基、氟取代烷基或芳基）中选择的一个原子或基团；Y是从—CO—、—SO2—、—SO—、—CONH—、—COO—、—（CF2）l—（其中l为1至10的整数）和—C(CF3)2—中选择的至少一个结构；Z是从直接键、—O—和—S—中选择的至少一个结构；R20是含氮杂环基团；q是1至5的整数；p是0至4的整数。
• Synthesis and Ring-Expanding Oligomerization of an Extremely Strained Macrocyclic Aromatic Ether−Sulfone
  作者：Howard M. Colquhoun、Zhixue Zhu、David J. Williams

  DOI：10.1021/ol010201n

  日期：2001.12.1

  4-C(6)H(4)SO(2)-1,4-C(6)H(4)O-1,3-C(6)H(4)O-1,4-C(6)H(4)SO(2)-1,4-C(6)H(4)-], synthesized by nickel-catalyzed intramolecular coupling of a bis-chlorophenylene-terminated precursor, undergoes fluoride-promoted ring expansion in dilute solution, giving a series of higher macrocyclic oligomers including cyclic dimer, trimer, and tetramer. The latter contains 20 aromatic residues in a 92-atom ring and is

  [反应：请参阅文本]一种极易拉紧的5环大环芳香醚砜[-1,4-C（6）H（4）SO（2）-1,4-C（6）H（4 ）O-1,3-C（6）H（4）O-1,4-C（6）H（4）SO（2）-1,4-C（6）H（4）-]，合成通过镍催化的双氯苯撑封端的前体的分子内偶联，在稀溶液中进行氟化物促进的环膨胀，得到一系列更高的大环低聚物，包括环状二聚体，三聚体和四聚体。后者在92个原子的环中包含20个芳香族残基，是晶体学上表征的最大的合成有机大环之一。还报道了相关大环醚酮的合成，结构和环扩展。