[Pd(CN)2(PMe3)2] | 25793-74-2

• 分子结构分类: 有机化合物
• 英文名称: [Pd(CN)2(PMe3)2]
• 英文别名: [Pd(CN)₂(PMe₃)₂]
• CAS: 25793-74-2
• 化学式: C₈H₁₈N₂P₂Pd
• 分子量: 310.612
• InChiKey: BUMLDZLYTVWXTH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三甲基氰硅烷 、 di(azido)bis(trimethylphosphine)palladium(II) 以 二氯甲烷 为溶剂， 以94%的产率得到[Pd(CN)2(PMe3)2]
  参考文献：
  名称：

  Reactivity of alkynyl Pd(II) azido complexes toward organic isocyanides, isothiocyanates, and nitriles

  摘要：

  Alkynyl Pd(II) azido complexes of the type [Pd(N-3)(CdropC-R)L-2] (1-3) were obtained by reactions of aqueous NaN3 with [Pd(Cl)(CdropC-R)L-2] (R = Ph or C(O)OMe). Treating compounds 1-3 with organic isocyanides (R-NC) afforded novel complexes, trans-[Pd(CdropC-Ph)(N=C=N-R)(PMe3)(2)] (R = 2,6-Me2C6H3 (4) or 2,6-Et2C6H3 (5)) and trans-[Pd(CdropC-R)(CN4-t-Bu)L-2] (6: L = PMe3, R = Ph; 7: L = PEt3, R = C(O)OMe; 8: L = PMe3 R = C(O)OMe), which contain either a carbodiimido or a C-coordinated tetrazolato group. Reactions of compounds 1 and 2 with R-N=C=S (R = 2,6-Me2C6H3 or CH2CH3) and 1,4-phenylene diisothiocyanate (C6H4(N=C=S)(2)) smoothly proceeded to give tetrazole-thiolato complexes, trans-[Pd(CdropCPh)(SCN4-R)L-2] (L = PMe3, R = Et (9) or 2,6-Me2C6H3 (10); L = PEt3, R = 2,6-Me2C6H3 (11)), and a phenylene-bridged dinuclear Pd(II) tetrazole-thiolato complex, [(PEt3)(2)(CdropCPh)Pd(SCN4-(mu-C6H4)-SCN4)Pd(CdropCPh)(PEt3)(2)] (12), respectively. Complexes 9-12 contain the Pd-S bond that is formed by the dipolar cycloaddition of the organic isothiocyanate to the Pd-azido bond. In contrast, the vcorresponding reactions of compounds land 2 with C6F5CN and Me3SiCN (organic nitriles, R-CN) gave an N-coordinated Pd(II)-tetrazolato compound {trans-[Pd(CdropC-Ph)(N4C-C6F5)(PMe3)(2)] (13)} and a mixture of Pd(II)-cyano complexes {trans[Pd(CdropC-Ph)(CN)(PEt3)(2)] (14) and [Pd(CN)2(PEt3)21 (15), respectively. Bis(phosphine) bis(cyano) complexes of Pd and Ni, [M(CN)(2)L-2] (L = PEt3, PMe3; L-2 = DEPE), could be obtained independently by the reactions of [M(N-3)(2)L-2] with excess Me3SiCN in organic solvents. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.09.056

文献信息

• Reactivities of organic isothiocyanates and thiocyanates toward dialkyl bis(phosphine) complexes of palladium(II) and platinum(II)
  作者：Seon Gye Lee、Keun-Young Choi、Yong-Joo Kim、SuJin Park、Soon W. Lee

  DOI：10.1016/j.poly.2014.10.020

  日期：2015.1

  Room-temperature reactions of trans-[PdEt2L2] (L = PMe3, PEt3, PMe2Ph) with organic isothiocyanates 1R-NCS; R = benzyl; CH(CH3)Ph, R-(-) and S-(+); indanyl, S-(+)] afforded the S,S-coordinated Pd(II) complexes [Pd(S2C=N-R)L-2] containing a dithiocarbonimidato (S2C--,--N-R) group. Similar reactions involving allyl isothiocyanates produced the cationic eta(3)-allyl Pd complex [Pd(eta(3)-allyl)(PMe3)(2)](+)(NCS)(-). When [Pd(S2C=N-R)(PMe3)(2)] was treated with 1 equiv of a chelating phosphine [L-L = depe (1,2-bis(diethylphosphino)ethane) and dmpe (1,2-bis(dimethylphosphino)ethane)1, the corresponding complexes [Pd(S2C=N-R)(L-L)] were produced. Reactions of trans-[PdEt2L2] (L = PMe3, PMe2Ph) with organic thiocyanates (R-SCN; R = benzyl, Et) resulted in the formation of [Pd(CN)(2)L-2] and an organic disulfide by S-C bond cleavage of R-SCN. However, similar reactions of the dimethyl analogs, trans-[PdMe2L2] (L = PMe3, PEt3), with benzyl thiocyanate afforded different products, [Pd(NCS)(2)L-2] or [PdMe(NCS)L-2]. Treating [Pt(styrene)(PMe3)(2)] with benzyl isothiocyanate gave the S-coordinated dithiocarbonimidato Pt(II) complex, [Pt(S2C=N-R)(Me3P)(2)] (R = benzyl). In contrast, cis-[PtEt2(PMe3)(2)] reacted with the isothiocyanate to afford the trialkyl Pt(IV) complex [PtEt2(SCN)(CH2Ph)(PMe3)(2)]. (C) 2014 Elsevier Ltd. All rights reserved.