[(triphenylphosphine)2Cu(HCO3)] | 73716-93-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(triphenylphosphine)2Cu(HCO3)]
• 英文别名: [(PPh3)2Cu(HCO3)]
• CAS: 73716-93-5
• 化学式: C₃₇H₃₁CuO₃P₂
• 分子量: 649.145
• InChiKey: KWOYKXMNVOAXIV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(triphenylphosphine)2Cu(HCO3)] 在 苯胺 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以79%的产率得到phenylcarbamatobis(triphenylphosphine)copper(I)
  参考文献：
  名称：

  Reactions of CO₂with Cu(I) Alkoxides and Amides to Give Alkylcarbonato-, μ-Carbonato-, Hydrogencarbonato-, and Carbamato-copper Complexes

  摘要：

  Carbon dioxide reacts with ROCu(PPh3)2 (R=C2H5, C6H5CH2; PPh3=triphenylphosphine) to produce ROCO2Cu(PPh3)2. Hydrolysis or thermolysis of the alkylcarbonatocopper(I) complexes gives a binuclear carbonatocopper(I) complex (PPh3)2CuOCO2Cu(PPh3)2, which is further converted into a hydrogencarbonatocopper(I) complex [HOCO2Cu(PPh3)2]n by the reaction with CO2 in moist solvents. The IR spectrum of [HOCO2Cu(PPh3)2]n shows association of the HOCO2Cu(PPh3)2 units through hydrogen bonds. The IR spectrum of [HOCO2Cu(PPh3)2]n also reveals that the mode of the association depends on conditions of the crystallization of the complex. The reaction of (PPh3)2CuOCO2Cu(PPh3)2 with CH3I gives (CH3O)2CO and the reaction of [HOCO2Cu(PPh3)2]n with C6H5NH2 affords C6H5NHCO2Cu(PPh3)2 in high yields. Carbon dioxide reacts also with an amidocopper(I) complex C6H5NHCu(PPh3)2 to yield a carbamatocopper(I) complex C6H5NHCO2Cu(PPh3)2. The reaction of CH3Cu(PPh3)2(diethyl ether)0.5 with CO2 in the presence of HN(C2H5)2 affords (C2H5)2NHCO2Cu(PPh3)2. The isocyanate group of phenyl isocyanate is inserted into the C2H5O–Cu bond of C2H5OCu(PPh3)2 to give a (ethyl N-phenylcarbamato)copper complex.

  DOI：

  10.1246/bcsj.53.680
• 作为产物：
  描述：

  phenoxobis(triphenylphosphine)copper(I) 在 二氧化碳 、 水 、 苯酚 作用下， 以 四氢呋喃 为溶剂， 以84%的产率得到[(triphenylphosphine)2Cu(HCO3)]
  参考文献：
  名称：

  Reactions of CO₂with Cu(I) Alkoxides and Amides to Give Alkylcarbonato-, μ-Carbonato-, Hydrogencarbonato-, and Carbamato-copper Complexes

  摘要：

  Carbon dioxide reacts with ROCu(PPh3)2 (R=C2H5, C6H5CH2; PPh3=triphenylphosphine) to produce ROCO2Cu(PPh3)2. Hydrolysis or thermolysis of the alkylcarbonatocopper(I) complexes gives a binuclear carbonatocopper(I) complex (PPh3)2CuOCO2Cu(PPh3)2, which is further converted into a hydrogencarbonatocopper(I) complex [HOCO2Cu(PPh3)2]n by the reaction with CO2 in moist solvents. The IR spectrum of [HOCO2Cu(PPh3)2]n shows association of the HOCO2Cu(PPh3)2 units through hydrogen bonds. The IR spectrum of [HOCO2Cu(PPh3)2]n also reveals that the mode of the association depends on conditions of the crystallization of the complex. The reaction of (PPh3)2CuOCO2Cu(PPh3)2 with CH3I gives (CH3O)2CO and the reaction of [HOCO2Cu(PPh3)2]n with C6H5NH2 affords C6H5NHCO2Cu(PPh3)2 in high yields. Carbon dioxide reacts also with an amidocopper(I) complex C6H5NHCu(PPh3)2 to yield a carbamatocopper(I) complex C6H5NHCO2Cu(PPh3)2. The reaction of CH3Cu(PPh3)2(diethyl ether)0.5 with CO2 in the presence of HN(C2H5)2 affords (C2H5)2NHCO2Cu(PPh3)2. The isocyanate group of phenyl isocyanate is inserted into the C2H5O–Cu bond of C2H5OCu(PPh3)2 to give a (ethyl N-phenylcarbamato)copper complex.

  DOI：

  10.1246/bcsj.53.680

文献信息

• Reaction of carbon dioxide with arylcopper(I) complexes containing tertiary phosphines
  作者：N. Marsich、A. Camus、G. Nardin

  DOI：10.1016/s0022-328x(00)95267-7

  日期：1982.11

  ArCuI compounds (Ar = phenyl, o-, m-, or p-tolyl) do not react with carbon dioxide at appreciable rate, but in the presence of triphenylphosphine in appropriate solvents undergo insertion to give the corresponding carboxylato complexes ArCO2Cu(PPh3)2. In the presence of diphos the carbon dioxide absorption was very slow and mainly gave (ArCO2Cu)2diphos3 complexes. The (diphenylphosphino)methane (DPM)

  ArCu I化合物（Ar =苯基，o-，m-或对甲苯基）不会以明显的速率与二氧化碳反应，但在三苯膦的存在下，在适当的溶剂中会插入，得到相应的羧基络合物ArCO 2 Cu（ PPh 3）2。在存在双酚的情况下，二氧化碳的吸收非常缓慢，并且主要产生（ArCO 2 Cu）2双酚3络合物。（二苯基膦基）甲烷（DPM）衍生物[ArCO 2 CuDPM] 2和（ArCO 2 Cu）2通过其他方法制备DPM进行比较。报道了HCO 2 Cu（PPh 3）2的X射线结构。
• Solution and mechanochemical syntheses, and spectroscopic and structural studies in the silver(i) (bi-)carbonate: triphenylphosphine system
  作者：Graham A. Bowmaker、Effendy、John V. Hanna、Peter C. Healy、Scott P. King、Claudio Pettinari、Brian W. Skelton、Allan H. White

  DOI：10.1039/c1dt10416k

  日期：——

  Syntheses of a number of adducts of silver(I) (bi-)carbonate with triphenylphosphine, both mechanochemically, and from solution, are described, together with their infra-red spectra, 31P CP MAS NMR and crystal structures. Ag(HCO3):PPh3 (1 : 4) has been isolated in the ionic form [Ag(PPh3)4](HCO3)·2EtOH·3H2O. Ag2CO3:PPh3 (1 : 4) forms a binuclear neutral molecule [(Ph3P)2Ag(O,μ-O′·CO)Ag(PPh3)2](·2H2O)

  多种加合物的合成 碳酸银（I） 和 三苯膦描述了机械化学和溶液化学方法，以及它们的红外光谱，31 P CP MAS NMR和晶体结构。银（HCO 3）：PPh 3已分离出离子形式[Ag（PPh 3）4 ]（HCO 3）·2EtOH·3H 2 O的（1：4）。银2 CO 3：PPh 3（1：4）形成双核中性分子[（Ph 3 P）2 Ag（O，μ- O '·CO）Ag（PPh 3）2 ]（·2H 2 O），而银（HCO 3）：PPh 3 （1：2）已分离为单核和双核形式：[（Ph 3 P）2 Ag（O 2 COH）]和[（Ph 3 P）2 Ag（μ- O ·CO·OH）2 Ag（PPh 3）2 ]（均未溶剂化）。一种更方便的方法来制备先前报道的铜（I） 复杂的 [（Ph 3 P）2铜（HCO 3）也有报道。