2-[3-(4-methoxycarbonylphenyl)acryloyl]-1,3-cyclopentanedione | 37756-16-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-[3-(4-methoxycarbonylphenyl)acryloyl]-1,3-cyclopentanedione
• 英文别名: 2-(3-(4-methoxycarbonylphenyl)acriloyl)-1,3-cyclopentanedion
• CAS: 37756-16-4
• 化学式: C₁₆H₁₄O₅
• 分子量: 286.284
• InChiKey: YFRZZFAVOKBGKB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  21.0
• 可旋转键数：
  4.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  77.51
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  2-[3-(4-methoxycarbonylphenyl)acryloyl]-1,3-cyclopentanedione 在 palladium on activated charcoal 氢气 作用下， 以 四氢呋喃 为溶剂， 生成 2-(4-Methoxycarbonylhydrocinnamoyl)-1,3-cyclopentanedione
  参考文献：
  名称：

  DE2161528

  摘要：

  公开号：
• 作为产物：
  描述：

  2-乙酰基环戊烷-1,3-二酮 、 对甲酰基苯甲酸甲酯 在 2-(4-吗啉基二硫代)苯并噻唑 作用下， 以 乙醇 为溶剂， 生成 2-[3-(4-methoxycarbonylphenyl)acryloyl]-1,3-cyclopentanedione
  参考文献：
  名称：

  DE2161528

  摘要：

  公开号：

文献信息

• Platinum(II) cationic complexes with derivatives of 2-acyl-1,3-cyclopentanedions
  作者：T. S. Khlebnikova、I. V. Merkushin、F. A. Lakhvich

  DOI：10.1134/s107036320605001x

  日期：2006.5

  cis-Diammineplatinum(II) complexes containing 2-acyl-1,3-cyclopentadion fragments as a bidentate acido ligand were prepared by the transformation of cis-diamminediiodoplatinum(II) to cis-diamminesulfatoplatinum(II) under the action of silver sulfate with the subsequent treatment of the resulting complex by barium hydroxide and by the reaction of the synthesized base with a twofold amount of 2-acyl-1,3-cyclopentanedion. The products are the cationic complexes of cis-diammineplatinum(II) and contain 2-acyl-1,3-cyclopentanedionate as a bidentate acido ligand, which chelates platinum atom by the carbonyl groups of side acyl chain and one group connected with five-membered cycle, whereas a 2-acyl-1,3-cyclopentadion enolate anion forms counter ion.
• Synthesis of (4-arylpyrrolidin-2-ylidene) derivatives of cyclic β-dicarbonyl compounds from cinnamoyl precursors
  作者：F. S. Pashkovskii、Yu. S. Dontsu、D. B. Rubinov、F. A. Lakhvich、V. F. Traven’、A. M. Borunov

  DOI：10.1134/s1070428014110116

  日期：2014.11

  1,4-Conjugate Michael addition of nitromethane to the enone fragment of cinnamoyl derivatives of carbo- and heterocyclic beta-dicarbonyl compounds provided the corresponding nitromethyl derivatives. The chemoselective reduction of the nitro group in the latter afforded 4-arylpyrrolidin-2-ylidene derivatives of beta-dicarbonyl compounds in high yield. The reaction products with the heterocyclic beta-dicarbonyl fragment are formed as equilibrium mixture of E- and Z-rotamers in which the E-rotamer predominates.