[Co(2,3,8,9-tetraphenyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene)(H2O)2]SO4 | 195989-72-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪烷类
• 英文名称: [Co(2,3,8,9-tetraphenyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene)(H2O)2]SO4
• CAS: 195989-72-1
• 化学式: C₃₂H₃₂CoN₄O₂*O₄S
• 分子量: 659.688
• InChiKey: ZHSFJEHIXPYKPG-SWJZZKFDSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cobalt(II) sulfate 、 2,3,8,9-tetraphenyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene 以 乙醇 为溶剂， 以75%的产率得到[Co(2,3,8,9-tetraphenyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene)(H2O)2]SO4
  参考文献：
  名称：

  Synthesis and Spectral Studies of Nickel(II) and Cobalt(II) Complexes of a Twelve-Membered and Tetradentate Macrocyclic Ligand

  摘要：

  Nickel(II) and cobalt(II) complexes of the general compositions Mt Tptacdte)X-2 (Tptacdte = 2,3,8,9-tetrophenyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene; X = Ci, Br, SCN for Ni(ll) and X = Cl, NO,, SCN for Co(II) and Co(Tptacdte)SO4 .(H2O)(2) have been synthesized. The complexes have been characterized on the basis of elemental analyses, molar conductance measurements, magnetic susceptibility measurements, IR and electronic spectral studies. The complexes were found to stabilize an octahedral geometry for the Ni(II) complexes and a distorted octahedral geometry for the Co(II) complexes.

  DOI：

  10.1080/00945719708000249