(2-(p-tolyl)pyridinato)(xanthato)rhodium(III) | 1415327-37-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: (2-(p-tolyl)pyridinato)(xanthato)rhodium(III)
• CAS: 1415327-37-5
• 化学式: C₂₆H₂₃N₂ORhS₂
• 分子量: 546.519
• InChiKey: PVECOJBVCCFKQT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二硫化碳 、 [{Rh(μ-Cl)(2-(p-tolyl)pyridinato)2}2] 、 sodium methylate 以 甲醇 为溶剂， 反应 1.0h， 以96%的产率得到  (2-(p-tolyl)pyridinato)(xanthato)rhodium(III)
  参考文献：
  名称：

  Synthesis and structural characterization of bis-cyclometalated complexes [M(ptpy)2(S2COCH3)] (M=Rh, Ir; ptpy=2-(p-tolyl)pyridinato)

  摘要：

  The synthesis of the bis-cyclometalated complexes [M(ptpy)(2)(S2COCH3)] (M = Rh, 1; M = Ir, 2; ptpy = 2-(p-tolyl)pyridinato) from [{M(mu-Cl)(ptpy)(2)}(2)], carbon disulfide and sodium methanolate as the base are described. Compound 1 and 2, respectively, were crystallized from dichloromethane/methanol and the molecular structures of both complexes were confirmed by single-crystal X-ray diffraction studies (both monoclinic, P2(1)/c). The emission spectrum of 1 exhibited the new compound as a red-emitting complex. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.08.032