2-carbamoyl-cyclohex-1-enecarboxylic acid | 81951-65-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-carbamoyl-cyclohex-1-enecarboxylic acid
• 英文别名: 2-Carbamoyl-cyclohex-1-encarbonsaeure；2-Carbamoyl-1-cyclohexene-1-carboxylic acid；2-carbamoylcyclohexene-1-carboxylic acid
• CAS: 81951-65-7
• 化学式: C₈H₁₁NO₃
• 分子量: 169.18
• InChiKey: VWFXHFHEOSNVQR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  80.4
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 ammonium hydroxide 作用下， 生成 2-carbamoyl-cyclohex-1-enecarboxylic acid
  参考文献：
  名称：

  Kuester, Hoppe-Seyler's Zeitschrift fur Physiologische Chemie, 1908, vol. 55, p. 519,520, 522

  摘要：

  DOI：

文献信息

• TETRAHYDROPHTHALAMIDE DERIVATIVE, INTERMEDIATE FOR PRODUCING THE SAME, PRODUCTION OF BOTH, AND HERBICIDE CONTAINING THE SAME AS ACTIVE INGREDIENT
  申请人：SAGAMI CHEMICAL RESEARCH CENTER

  公开号：EP0635485A1

  公开（公告）日：1995-01-25

  A 3,4,5,6-tetrahydrophthalamide derivative and a 3,4,5,6-tetrahydroisophthalimide derivative, both having an excellent efficay as the active ingredient of a herbicide, and an industrial process for efficiently producing these higher-performance, herbicidally active compounds. A tetrahydrophthalamide derivative represented by general formula (I) is produced by the reaction of a tetrahydrophthalimide derivative, prepared by the reaction of a halogenated 5-cycloalkyloxyaniline derivative with 3,4,5,6-tetrahydrophthalic anhydride, or of the tetrahydroisophthalimide derivative of the invention with various amines. These tetrahydrophthalamide and tetrahydroisophthalimide derivatives have an excellent herbicidal effect in the treatment of lowland and upland soils and foliage treatment. The tetrahydroisophthalimide derivative is useful also as an intermediate for producing the tetrahydrophthalamide derivative and the like.

  一种3,4,5,6-四氢邻苯二甲酰胺衍生物和一种3,4,5,6-四氢异邻苯二甲酰亚胺衍生物，这两种衍生物作为除草剂的活性成分具有极佳的功效，以及一种高效生产这些性能更佳、除草活性更强的化合物的工业工艺。通过卤化 5-环烷氧基苯胺衍生物与 3,4,5,6-四氢邻苯二甲酸酐反应制备的四氢邻苯二甲酰亚胺衍生物，或本发明的四氢异邻苯二甲酰亚胺衍生物与各种胺反应制备通式 (I) 所代表的四氢邻苯二甲酰亚胺衍生物。这些四氢邻苯二甲酰胺和四氢异邻苯二甲酰亚胺衍生物在处理低地和高地土壤和叶片方面具有极佳的除草效果。四氢异邻苯二甲酰亚胺衍生物还可用作生产四氢邻苯二甲酰胺衍生物等的中间体。
• Solid-phase affinity-based method for preparing and manipulating an analyte-containing solution
  申请人：Stolowitz Mark L.

  公开号：US20090215192A1

  公开（公告）日：2009-08-27

  A method for preparing an analyte-containing solution, which is compatible with surface-tension-directed liquid droplet manipulation and solid-phase affinity-based assays, is disclosed. The method comprises providing an affinity capture surface comprising a substrate surface having a plurality of first and second surface modifiers associated therewith, wherein the first and second surface modifiers render the affinity capture surface wettable and resistant to non-specific protein adsorption, and wherein the second surface modifiers are capable of selectively retaining an analyte, contacting the affinity capture surface with the analyte to form analyte/surface modifier complexes between the analyte and the second surface modifiers, and cleaving the first and second surface modifiers to release terminal portions of the first and second surface modifiers and the analyte into a solution in contact with the affinity capture surface, thereby yielding the analyte-containing solution and generating a hydrophobic surface. Novel affinity capture surfaces and methods for preparing the same are also disclosed.
• US5385925A
  申请人：——

  公开号：US5385925A

  公开（公告）日：1995-01-31
• US5506190A
  申请人：——

  公开号：US5506190A

  公开（公告）日：1996-04-09
• US5554581A
  申请人：——

  公开号：US5554581A

  公开（公告）日：1996-09-10