1,9-(4-Hydroxycyclohexano)buckminsterfullerene | 819870-97-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 1,9-(4-Hydroxycyclohexano)buckminsterfullerene
• CAS: 819870-97-8
• 化学式: C₆₄H₈O
• 分子量: 792.767
• InChiKey: TYNZYUNGPLPSQH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.84
• 重原子数：
  65.0
• 可旋转键数：
  0.0
• 环数：
  33.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  20.23
• 氢给体数：
  1.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  N-叔丁氧羰基-L-谷氨酸 1-苄酯 、 1,9-(4-Hydroxycyclohexano)buckminsterfullerene 在 4-二甲氨基吡啶 、 N,N'-二环己基碳二亚胺 作用下， 以 甲苯 为溶剂， 生成 、
  参考文献：
  名称：

  Synthesis of .alpha.-amino acid derivatives of C60 from 1,9-(4-hydroxycyclohexano)buckminsterfullerene

  摘要：

  A simple, high-yielding route to C60-derivatives of biological importance is presented.

  DOI：

  10.1021/jo00070a010
• 作为产物：
  描述：

  在 二异丁基氢化铝 作用下， 以 甲苯 为溶剂， 以93%的产率得到1,9-(4-Hydroxycyclohexano)buckminsterfullerene
  参考文献：
  名称：

  Synthesis of .alpha.-amino acid derivatives of C60 from 1,9-(4-hydroxycyclohexano)buckminsterfullerene

  摘要：

  A simple, high-yielding route to C60-derivatives of biological importance is presented.

  DOI：

  10.1021/jo00070a010

文献信息

• Metal-induced conformational changes in calix[n]arenes can control the electron-transfer efficiency between porphyrin and [60]fullerene in an on-off manner
  作者：Masaru Kawaguchi、Atsushi Ikeda、Itaru Hamachi、Seiji Shinkai

  DOI：10.1016/s0040-4039(99)01750-5

  日期：1999.11

  Calix[n]aryl esters (1(n):n=4 and 6) bearing a Zn(II)-porphyrin group as a fluorophore and a [60]fullerene group as a quencher on the lower rim were synthesized. In 1(6) a metal-induced 1,2,3-alternate-to-cone conformational change shortened the distance between these two groups and the electron-transfer efficiency was sharply increased. In 1(4) the electron-transfer efficiency was slightly increased in spite of a metal-induced rotation of the carbonyl groups which enlarges the distance between these two groups. These are novel responsive systems to control the electron-transfer efficiency between porphyrin and [60]fullerene. (C) 1999 Elsevier Science Ltd. All rights reserved.