3-(2-formyl-thiophen-3-yl)propionic acid ethyl ester | 1042742-51-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 3-(2-formyl-thiophen-3-yl)propionic acid ethyl ester
• CAS: 1042742-51-7
• 化学式: C₁₀H₁₂O₃S
• 分子量: 212.269
• InChiKey: DDUIALDTZBDABV-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  生成 3-(2-formyl-thiophen-3-yl)propionic acid ethyl ester
  参考文献：
  名称：

  Hydroarylation of acetylenes, acrylates, and isocyanates with heteroaromatic compounds under rhenium catalysis

  摘要：

  With the aid of a directing group, an imine moiety, heteroaromatic compounds add to acetylenes in the presence of a catalytic amount of [ReBr(CO)(3)(THF)](2) at the adjacent position of the directing group regioselectively to give hydroarylation of the acetylenes in good to excellent yields. Similarly, heteroaromatic compounds react with acrylates and isocyanates to give the corresponding hydroarylation products under rhenium catalysis. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.01.145