4-dodecyloxy-3,5-bis(2-trimethylsilylphenyliminomethyl)phenylacetylene | 1427772-65-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 4-dodecyloxy-3,5-bis(2-trimethylsilylphenyliminomethyl)phenylacetylene
• 英文别名: 1-[2-dodecoxy-5-ethynyl-3-[(2-trimethylsilylphenyl)iminomethyl]phenyl]-N-(2-trimethylsilylphenyl)methanimine
• CAS: 1427772-65-3
• 化学式: C₄₀H₅₆N₂OSi₂
• 分子量: 637.068
• InChiKey: VZQAGCXLUVNAEK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.56
• 重原子数：
  45
• 可旋转键数：
  19
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  34
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  N-(2-溴苯基)-O-苄基氨基甲酸酯 在 aluminum oxide 、 正丁基锂 作用下， 以 乙醚 、 正己烷 、 甲苯 为溶剂， 反应 61.0h， 生成 4-dodecyloxy-3,5-bis(2-trimethylsilylphenyliminomethyl)phenylacetylene
  参考文献：
  名称：

  Living-like helix-sense-selective polymerization of an achiral substituted acetylene having bulky substituents

  摘要：

  By using a new achiral phenylacetylene having bulky substituents as a monomer, living-like helix-sense-selective polymerization (HSSP) has been achieved. This is the first example of the HSSP of substituted acetylenes where the degree of polymerization was controlled. The resulting one-handed helical living polymer initiated polymerization of a second monomer to successfully yield a block copolymer. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2013.02.009

文献信息

• Living-like helix-sense-selective polymerization of an achiral substituted acetylene having bulky substituents
  作者：Yu Zang、Kazuki Nakao、Hiroki Yotsuyanagi、Toshiki Aoki、Takeshi Namikoshi、Toyokazu Tsutsuba、Masahiro Teraguchi、Takashi Kaneko

  DOI：10.1016/j.polymer.2013.02.009

  日期：2013.3

  By using a new achiral phenylacetylene having bulky substituents as a monomer, living-like helix-sense-selective polymerization (HSSP) has been achieved. This is the first example of the HSSP of substituted acetylenes where the degree of polymerization was controlled. The resulting one-handed helical living polymer initiated polymerization of a second monomer to successfully yield a block copolymer. (C) 2013 Elsevier Ltd. All rights reserved.