(meso-tetrakis(1-methylpyridinium-4-yl)porphinato)cobalt(II) | 127594-03-0

• 英文名称: (meso-tetrakis(1-methylpyridinium-4-yl)porphinato)cobalt(II)
• 英文别名: meso-tetrakis(1-methyl-4-pyridino)porphyrinato cobalt(II)；CoTM4PyP
• CAS: 127594-03-0
• 化学式: C₄₄H₃₆CoN₈
• 分子量: 735.817
• InChiKey: IBZSPQQFRGPKKP-DAJBKUBHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cobalt(III)-5,10,15,20-tetra(N-methyl-4-pyridyl)porphine 在 sodium dithionite 作用下， 以 水 为溶剂， 生成 (meso-tetrakis(1-methylpyridinium-4-yl)porphinato)cobalt(II)
  参考文献：
  名称：

  锰卟啉的光化学。第3部分：mn II / Mn III的互变

  摘要：

  连二亚硫酸盐可在水溶液中还原水溶性Mn III卟啉。还原速率与pH无关，但是显示出对水溶性基团性质的显着依赖性。反应机理涉及亚硫酸根自由基阴离子（SO [图示省略]）对卟啉环外围的外球攻击，以形成Mn III卟啉π-自由基阴离子，其迅速重排成Mn II卟啉。

  DOI：

  10.1039/f29807601415
• 作为试剂：
  描述：

  六氨合钌 、 氧气 在 (meso-tetrakis(1-methylpyridinium-4-yl)porphinato)cobalt(II) 作用下， 以 not given 为溶剂， 生成 hexaammineruthenium(III) 、 双氧水
  参考文献：
  名称：

  氧化还原聚合物电极上的电催化，催化作用和电荷传播作用分离。在四（4-N-甲基吡啶基）卟啉钴（II）催化下将分子氧还原为过氧化氢

  摘要：

  Donnees sur la cinetique de reduction d'O 2 par Ru(NH 3 ) 6 2+ , catalysee par la Coco(II) tetrakis (4-N-methylpyridyl) porphyrine, en solution homogene et lorsque les reactifs sont confines sur les revetements de Nafion sur des电极石墨

  DOI：

  10.1021/ja00298a008

文献信息

• Oxidation of cyclohexene with molecular oxygen catalyzed by cobalt porphyrin complexes immobilized on montmorillonite
  作者：Hideyuki Kameyama、Fumitaka Narumi、Tetsutaro Hattori、Hiroshi Kameyama

  DOI：10.1016/j.molcata.2006.05.022

  日期：2006.10

  Composite materials were prepared by intercalating cationic porphyrinato cobalt complexes with the substituents of the quaternary ammonium salt of heterocyclic amine into a montmorillonite interlayer. Using these clay interlayer-fixed porphyrinato cobalt complexes as catalyst, the epoxidation of cyclohexene by oxygen molecules was examined. The prepared intercalation compounds have mesopores with an average diameter of about 12 nm, and their specific surface area increased in proportion to the amount of the intercalated porphyrinato cobalt complexes. It was proven that the porphyrinato, cobalt complex was intercalated between montmorillonite layers functioned as a pillaring agent. A pillared clay catalyst, which was prepared by intercalating a [meso-tetrakis(1-ethyl-3-pyridinio)porphyrinato] cobalt complex into the montmorillonite interlayer, showed the highest catalytic activity forming 1,2-epoxycyclohexane preferentially in the presence of isobutyraldehyde. It is suggested that montmorillonite contributes to the stabilization of the porphyrinato cobalt complex, and also plays a role in accelerating oxidation by activating oxygen molecules by way of constructing a reaction field that is regulated three-dimensionally through electrostatic interaction with guest molecules. (c) 2006 Elsevier B.V. All rights reserved.
• Activation parameters and a mechanism for metal-porphyrin formation reactions
  作者：Jafara Turay、Peter Hambright

  DOI：10.1021/ic50204a059

  日期：1980.2
• Reddy, Damodar; Mukherjee, Arka; Chandrashekar, T. K., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1990, vol. 29, # 4, p. 312 - 315
  作者：Reddy, Damodar、Mukherjee, Arka、Chandrashekar, T. K.

  DOI：——

  日期：——